太阳能学报
太暘能學報
태양능학보
ACTA ENERGIAE SOLARIS SINICA
2001年
2期
196-199
,共4页
颜秀茹%郭伟巍%宋宽秀%霍明亮%王建萍
顏秀茹%郭偉巍%宋寬秀%霍明亮%王建萍
안수여%곽위외%송관수%곽명량%왕건평
纳米TiO2%光催化活性%制备和表征
納米TiO2%光催化活性%製備和錶徵
납미TiO2%광최화활성%제비화표정
以SiO2为载体,在酸性条件下,用TiCl4水解法制备了TiO2纳米膜催化剂TiO2/SiO2。以IR、XRD、SEM和吸光光度法对其进行了表征,所制TiO2膜的平均粒径在12nm以内,并能在很宽的煅烧温度范围内保持锐钛矿晶体结构;将TiO2/SiO2应用于光催化降解敌敌畏(DDVP),具有高的光催化活性,且易回收及反复使用。探讨了不同条件对光催化活性的影响。
以SiO2為載體,在痠性條件下,用TiCl4水解法製備瞭TiO2納米膜催化劑TiO2/SiO2。以IR、XRD、SEM和吸光光度法對其進行瞭錶徵,所製TiO2膜的平均粒徑在12nm以內,併能在很寬的煅燒溫度範圍內保持銳鈦礦晶體結構;將TiO2/SiO2應用于光催化降解敵敵畏(DDVP),具有高的光催化活性,且易迴收及反複使用。探討瞭不同條件對光催化活性的影響。
이SiO2위재체,재산성조건하,용TiCl4수해법제비료TiO2납미막최화제TiO2/SiO2。이IR、XRD、SEM화흡광광도법대기진행료표정,소제TiO2막적평균립경재12nm이내,병능재흔관적단소온도범위내보지예태광정체결구;장TiO2/SiO2응용우광최화강해활활외(DDVP),구유고적광최화활성,차역회수급반복사용。탐토료불동조건대광최화활성적영향。
The TiO2/SiO2 photocatalysts have been prepared by hydrolysis of TiCl4 in acid conditions,and characterized by IR,XRD,SEM and photometry.The TiO2 film kept anatase form in wide range of temperature,and its average diameter was within 12 nm. They had high activity in degrading DDVP,and were easy to be recycled and reused.The photocatalytic activity under diferrent preparing conditions were also studied