CAJ | 학술논문

将CoO、NiO、CuO、FeO等多种密着剂引入到搪瓷釉,采用B2O3、TiO2等取代部分SiO2、Al2O3,研制出搪瓷烧成温度低、密着性能优良的低温搪瓷。通过场发射扫描电镜和能谱仪分析表明,密着性能优良的低温搪瓷界面存在搪瓷釉层与金属铁层相互镶嵌和Fe、Si、Co、Ni、Na、K、O等元素相互扩散的中间过渡层,中间过渡层的存在为低温搪瓷产生优良密着创造条件。
장CoO、NiO、CuO、FeO등다충밀착제인입도당자유,채용B2O3、TiO2등취대부분SiO2、Al2O3,연제출당자소성온도저、밀착성능우량적저온당자。통과장발사소묘전경화능보의분석표명,밀착성능우량적저온당자계면존재당자유층여금속철층상호양감화Fe、Si、Co、Ni、Na、K、O등원소상호확산적중간과도층,중간과도층적존재위저온당자산생우량밀착창조조건。
Low temperature enamel with excellence adherence has been developed by introducing adherence agents,such as CoO,NiO,CuO,FeO and replacing SiO2,Al2O3 by B2O3,TiO2.There exists interlay structure and inter-diffusion elements of Fe,Si,Co,Ni,Na,K,O in the interface between enamel and metal which has been revealed by SEM and Energy Spectrometer analysis,which results in the strong adherence between interlays.