CAJ | 학술논문

为探索铝掺杂羟基磷灰石（Al-HA）的结晶特点,以硝酸钙、硝酸铝和磷酸二氢铵反应所获沉淀为前驱物,以水为介质在不同的Al掺杂量下进行了水热合成实验。利用X射线衍射（XRD）和拉曼光谱（Raman）对所得样品进行表征。结果表明,水热反应能获得Al-HA纳米晶,Al掺杂量的增大会抑制羟基磷灰石（HA）晶粒度长大,当掺量超过10时HA会向非结晶态转化。随着Al掺杂量的提高,HA的拉曼光谱的振动峰431 cm-1、591 cm-1、961 cm-1、1 046 cm-1先逐渐减弱,HA的结晶度下降。最后431 cm-1、591 cm-1、1 046 cm-1处振动峰消失,并在1 111.5 cm-1处出现新的振动峰,说明掺铝量宜在于5以下。
위탐색려참잡간기린회석（Al-HA）적결정특점,이초산개、초산려화린산이경안반응소획침정위전구물,이수위개질재불동적Al참잡량하진행료수열합성실험。이용X사선연사（XRD）화랍만광보（Raman）대소득양품진행표정。결과표명,수열반응능획득Al-HA납미정,Al참잡량적증대회억제간기린회석（HA）정립도장대,당참량초과10시HA회향비결정태전화。수착Al참잡량적제고,HA적랍만광보적진동봉431 cm-1、591 cm-1、961 cm-1、1 046 cm-1선축점감약,HA적결정도하강。최후431 cm-1、591 cm-1、1 046 cm-1처진동봉소실,병재1 111.5 cm-1처출현신적진동봉,설명참려량의재우5이하。
In order to quest for the crystal character of Aluminum-Substituted Hydroxyapatite,hydrothermal synthesis hydroxyapatite was experimented using Ca（NO3）2,（NH4）H2PO4 and Al（NO3）3 as raw materials,water as reaction medium,in an autoclave at Al doped with different.The HA sample was characterized by X-ray diffraction（XRD） and Raman spectroscopy.The results show that the hydrothermal reaction can get Aluminum-Substituted Hydroxyapatite,Al doping increases the grain size inhibits the growth of HA,when more than 10 of content to the hydroxyapatite conversion of non-crystalline state.With the increased amount of Al doping,the Raman spectroscopy of HA vibration peak of 431cm-1,591cm-1,961cm-1,1046cm-1 decreased gradually at first,decreased the crystallinity of HA.Finally,431cm-1,591cm1,1 046cm-1 vibration peak disappeared,and in 1 111.5cm-1 occurring at the peak of the new vibration,that is doped with aluminum content should be below 5.