广东化工
廣東化工
엄동화공
GUANGDONG CHEMICAL INDUSTRY
2011年
10期
17-19
,共3页
含酚废水%废水处理%煤气化废水%混凝%Fenton氧化
含酚廢水%廢水處理%煤氣化廢水%混凝%Fenton氧化
함분폐수%폐수처리%매기화폐수%혼응%Fenton양화
wastewater containing phenol%wastewater treatment%coagu-flocculation%fenton oxidation
煤气化高浓度含酚废水属于"高危"难处理的工业废水。文章采用混凝-Fenton氧化-混凝联合工艺对高浓度煤气化废水进行预处理,考查了影响处理效果的主要因素。结果表明,采用硫酸铁混凝处理,挥发酚去除率仅有57%;当酚/铁比为1:4,双氧水(30%)投加量10 mL/L,聚合氯化铝投加量为1 g/L时,采用联合工艺处理挥发酚和COD的去除率分别达96%和94%以上。若在氧化后利用剩余活性污泥进行吸附处理,处理效果进一步提高,挥发酚和COD的去除率分别达99%和97%以上,色度小于10倍。
煤氣化高濃度含酚廢水屬于"高危"難處理的工業廢水。文章採用混凝-Fenton氧化-混凝聯閤工藝對高濃度煤氣化廢水進行預處理,攷查瞭影響處理效果的主要因素。結果錶明,採用硫痠鐵混凝處理,揮髮酚去除率僅有57%;噹酚/鐵比為1:4,雙氧水(30%)投加量10 mL/L,聚閤氯化鋁投加量為1 g/L時,採用聯閤工藝處理揮髮酚和COD的去除率分彆達96%和94%以上。若在氧化後利用剩餘活性汙泥進行吸附處理,處理效果進一步提高,揮髮酚和COD的去除率分彆達99%和97%以上,色度小于10倍。
매기화고농도함분폐수속우"고위"난처리적공업폐수。문장채용혼응-Fenton양화-혼응연합공예대고농도매기화폐수진행예처리,고사료영향처리효과적주요인소。결과표명,채용류산철혼응처리,휘발분거제솔부유57%;당분/철비위1:4,쌍양수(30%)투가량10 mL/L,취합록화려투가량위1 g/L시,채용연합공예처리휘발분화COD적거제솔분별체96%화94%이상。약재양화후이용잉여활성오니진행흡부처리,처리효과진일보제고,휘발분화COD적거제솔분별체99%화97%이상,색도소우10배。
Coal gasification high concentrations of phenols wastewater belong to "high-risk" tricky industrial wastewater.In the paper the coagu-flocculation-Fenton oxidation-coagulation joint process was employed to pretreat highly concentrated coal gasification wastewater,examines the main factors that affect the treatment effect.The results showed that removal rate of volatile phenols was only 57 % in direct coagulation treatment.When phenols/iron for 1:4,H2O2(30 %) dosing quantity 10 mL/L,polyaluminium chloride dosing quantity for 1 g/L,volatile phenols and COD removal rate by the combined process being more than 96 % and 94 % respectively,if by the coagulation-oxidation-adsorption-coagulation joint process,removal efficiency further increased to 99 % and 97 % above,chroma was less than 10 times.