CAJ | 학술논문

用动态扭振法对不同配比的(环氧树脂-聚酰胺)／聚(丙烯酸正丁酯-二乙烯苯-苯乙烯)互穿聚合物网络(IPN)进行了4个温度的等温固化实验。讨论了其最佳配方和最佳固化条件;求取了固化反应表观活化能ΔEa,讨论了不同组分对固化反应,特别是对ΔEa的影响。用非平衡态热力学涨落理论对上述IPN的等温固化行为进行了预估,理论曲线与实验曲线符合良好。
용동태뉴진법대불동배비적(배양수지-취선알)／취(병희산정정지-이을희분-분을희)호천취합물망락(IPN)진행료4개온도적등온고화실험。토론료기최가배방화최가고화조건;구취료고화반응표관활화능ΔEa,토론료불동조분대고화반응,특별시대ΔEa적영향。용비평형태열역학창락이론대상술IPN적등온고화행위진행료예고,이론곡선여실험곡선부합량호。
Isothermal cure experiments of(epoxy-polyamide)／poly(butyl acrylate-divinylbenzene-styrene) interpenetrating polymer networks(IPN) were carried out by the dynamic torsional vibration method at four temperatures. The optimum composition and curing conditions were estimated. Apparent activation energy ΔEa of cure reaction was calculated and influences of different components on the cure reaction and ΔEa were discussed. A nonequilibrium thermodynamic fluctuation theroy has been applied to predict isothermal cure behavior of IPN. There was a good agreement between the theoretical curve and the experimental one.