分析化学
分析化學
분석화학
CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
2001年
6期
710-712
,共3页
詹心琪%李东辉%朱庆枝%郑洪%许金钩
詹心琪%李東輝%硃慶枝%鄭洪%許金鉤
첨심기%리동휘%주경지%정홍%허금구
四磺基铝酞菁%乙醇%酒
四磺基鋁酞菁%乙醇%酒
사광기려태정%을순%주
基于四磺基铝酞菁 (AlS4Pc) 在阳离子表面活性剂存在下发生诱导缔合而导致体系荧光猝灭,而在乙醇存在下AlS4Pc解聚而使体系荧光恢复的原理,建立了测定白酒中乙醇含量的新方法。方法的线性区间为0.5%~90%(V/V)乙醇,检测限为0.48%(V/V)。本法已应用于实际酒样中乙醇的直接测定,结果满意
基于四磺基鋁酞菁 (AlS4Pc) 在暘離子錶麵活性劑存在下髮生誘導締閤而導緻體繫熒光猝滅,而在乙醇存在下AlS4Pc解聚而使體繫熒光恢複的原理,建立瞭測定白酒中乙醇含量的新方法。方法的線性區間為0.5%~90%(V/V)乙醇,檢測限為0.48%(V/V)。本法已應用于實際酒樣中乙醇的直接測定,結果滿意
기우사광기려태정 (AlS4Pc) 재양리자표면활성제존재하발생유도체합이도치체계형광졸멸,이재을순존재하AlS4Pc해취이사체계형광회복적원리,건립료측정백주중을순함량적신방법。방법적선성구간위0.5%~90%(V/V)을순,검측한위0.48%(V/V)。본법이응용우실제주양중을순적직접측정,결과만의
A new fluorimetric method was developed for the determi nation of ethanol in alcoholic beverage. The method is based on the principle that tetrasubstituted sulphonated aluminum phthalocyanine (AlS4Pc), a red-r egion fluorescent reagent, is induced to associate in the presence of cationic s urfactant, cetyltrimethylammonium bromide (CTMAB), thus its fluorescence is quen ched, and then the aggregate is disaggregated by the a ddition of ethanol and the fluorescence is recovered. This method has a linear determination range of 0.5%~90.0%(V/V), the detection limit is 0.48%(V /V). The method has been used to determine real alcoholic beverage samples w ith satisfactory results.