CAJ | 학술논문

采用固相法合成了尖晶石型LiMn2O4,并通过溶胶-凝胶法制备了不同物质的量的百分比含量Li4Ti5O12包覆的正极材料.X-射线衍射和扫描电镜结果表明,Li4Ti5O12微粒包覆在LiMn2O4的表面没有产生晶体结构的变化.实验电池在室温下,以1C,2C和5C倍率作充放电循环测试;结果表明,与未包覆的LiMn2O4相比,表面包覆Li4Ti5O12微粒的正极材料在高倍率下具有更好的循环稳定性.
채용고상법합성료첨정석형LiMn2O4,병통과용효-응효법제비료불동물질적량적백분비함량Li4Ti5O12포복적정겁재료.X-사선연사화소묘전경결과표명,Li4Ti5O12미립포복재LiMn2O4적표면몰유산생정체결구적변화.실험전지재실온하,이1C,2C화5C배솔작충방전순배측시;결과표명,여미포복적LiMn2O4상비,표면포복Li4Ti5O12미립적정겁재료재고배솔하구유경호적순배은정성.
Spinel LiMn2O4 was prepared by solid-state reaction and coated with different molar ratios of Li4Ti5O12 particles via sol-gel method. The unmodified and surface-modified LiMn2O4 were characterized by XRD and SEM.The results suggest that the Li4Ti5O12 particles have been encapsulated on the surface of the LiMn2O4 without any crystal structural change. To investigate the rate capability of the prepared materials, the experimental batteries were performed under a current rate of 1C, 2C and 5C, respectively, at ambient temperature. The electrochemical results reveal that the Li4Ti5O12-coated LiMn2O4 materials show excellent rate stability compared to the uncoated spinel, especially under 5C rate.