无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2010年
5期
926-930
,共5页
朱兴城%丁亚洲%张奇龙%朱必学
硃興城%丁亞洲%張奇龍%硃必學
주흥성%정아주%장기룡%주필학
2,2'-(2-氨基-苯氧基)乙醚%配合物%晶体结构
2,2'-(2-氨基-苯氧基)乙醚%配閤物%晶體結構
2,2'-(2-안기-분양기)을미%배합물%정체결구
2,2'-(2-amino-phenoxv)-ether%complex%crvstal structure
The compound 2,2'-(2-amino-phenoxy)-ether[L]was synthesized from the reaction of diethylene glycol with tosyl chloride.AgClO4 and ZnCl2 each react with L to give two complexes[Ag2L2(H2O)(ClO4)2](1) and [ZnLCl2]n (2)respectively,and characterized by FTIR and single crystal X-ray diffraction.The results of structural analysis indicated that both complexes crystallize in the monoclinic system with space group P21/c.1 is a dinuclear complex,and 2 forming 1 D zigzag chain by Zn(Ⅱ)linking aajacent ligands in turn.When viewed from the top of the chain,the structure of 2 shows the unidimensional tube.CCDC:748592,1;748594,2.
