CAJ | 학술논문

由H+(H2O)2.5阳离子,[Ni(H2O)8]2+阳离子,[PW12O40]3-阴离子和异烟酸氮氧化物(HINO)自组装成一个具有质子导电性的化合物{[Ni(H2O)8][H(H2O)2.5](HINO)4(PW12O40)｝n.293 K的单晶X-射线衍射分析表明标题化合物形成1个带有一维通道的三维氢键网络结构.[PW12O40]3-阴离子填充在一维通道内并且自组装成多阴离子链.热重分析表明在20～100℃范围内化合物没有矢重,表明化合物结构单元内所有的水分子在100℃以下不易失去.标题化合物在85～100℃范围内表现出好的离子导电性(1×10-3～2×10-3 S·cm-1).
유H+(H2O)2.5양리자,[Ni(H2O)8]2+양리자,[PW12O40]3-음리자화이연산담양화물(HINO)자조장성일개구유질자도전성적화합물{[Ni(H2O)8][H(H2O)2.5](HINO)4(PW12O40)｝n.293 K적단정X-사선연사분석표명표제화합물형성1개대유일유통도적삼유경건망락결구.[PW12O40]3-음리자전충재일유통도내병차자조장성다음리자련.열중분석표명재20～100℃범위내화합물몰유시중,표명화합물결구단원내소유적수분자재100℃이하불역실거.표제화합물재85～100℃범위내표현출호적리자도전성(1×10-3～2×10-3 S·cm-1).
A proton-conductive complex {[Ni(H2O)8][H(H2O)2.5](HINO)4(PW12O40)}n,was constructed by a self-assembly of cations,[Ni(H2O)8]2+ cations,[PW12O40]3-anions and isonicotinic acid N-oxide (HINO).Single-crystal X-ray diffraction analysis at 293 K revealed that the title complex presented exactly a three-dimensional (3D) hydrogen-bonded network with large one-dimensional (1D) channels.Interestingly,[PW12O40]3-anions just filled in the 1D channels and self-assembled into poly-Keggin-anion chains.Thermogravimetric analysis shows no weight loss in the temperature range of 20～100 ℃,indicating that all water molecules in the unit structure are not easily lost below 100 ℃.The title complex was characterized by a satisfactory ionic conductivity (1×10-3～2×10-3 S·cm-1) in the temperature range 85 to 100 ℃.CCDC:825709.