CAJ | 학술논문

对中国南海海绵中的新化合物19-methoxy-scalarin进行1H和13C NMR谱的全归属, 并运用"激发雕刻"技术,利用1D GOESY实验确定该化合物立体构型.实验结果亦表明1D GOESY实验选择性好,提供的信息更加直观、清晰,是化合物立体结构确定的好方法.
대중국남해해면중적신화합물19-methoxy-scalarin진행1H화13C NMR보적전귀속, 병운용"격발조각"기술,이용1D GOESY실험학정해화합물입체구형.실험결과역표명1D GOESY실험선택성호,제공적신식경가직관、청석,시화합물입체결구학정적호방법.
A new diterpenoid, 19-methoxy-scalarin, was isolated from marine sponge Hyrtios erectus. Its structure was determined by 1D and 2D NMR spectroscopy. In combination with the "excitation sculpting" technique, 1D GOESY was used for its configuration determination. The experimental results show that, compared to the commonly used NOE difference method, 1D GOESY provides a more direct and easy way for configuration determination.