CAJ | 학술논문

采用乙醇还原法制备了金属Pt/三苯胺烯共轭分子纳米复合物(Pt@DPSDA),通过UV-vis、TEM、FTIR、XRD、荧光、光电化学等方法对纳米复合物进行了表征.三苯胺烯分子通过分子末端羧基与金属Pt纳米粒子表面原子相互作用,形成以金属Pt纳米粒子为核,三苯胺烯分子为壳的核/壳型纳米复合物.光照下纳米复合物中激发态有机分子与金属Pt纳米粒子之间具有较好的电子转移作用,Pt@DPSDA纳米复合物可以作为催化剂在紫外-可见光照下分解水获得氢气.
채용을순환원법제비료금속Pt/삼분알희공액분자납미복합물(Pt@DPSDA),통과UV-vis、TEM、FTIR、XRD、형광、광전화학등방법대납미복합물진행료표정.삼분알희분자통과분자말단최기여금속Pt납미입자표면원자상호작용,형성이금속Pt납미입자위핵,삼분알희분자위각적핵/각형납미복합물.광조하납미복합물중격발태유궤분자여금속Pt납미입자지간구유교호적전자전이작용,Pt@DPSDA납미복합물가이작위최화제재자외-가견광조하분해수획득경기.
Platinum/triphenylamine ethylene nanocomposite (Pt@DPSDA) was prepared using an ethanol reduction method and characterized with UV-vis,TEM,FTIR,XRD,fluorescence spectroscopy,and photo-electrochemical method,respectively.Platinum core/conjugated organic molecule shell nanocomposite was formed as DPSDA molecules attached to the surface Pt atoms of platinum nanoparticles through carboxyl groups.DPSDA molecules in excited state may transfer photo-electron to the platinum nanoparticle.Under irradiation of UV-vis light,hydrogen was produced from photodecomposition of water using Pt@DPSDA nanocomposite as the catalyst.