北京化工大学学报(自然科学版)
北京化工大學學報(自然科學版)
북경화공대학학보(자연과학판)
JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY(NATURAL SCIENCE EDITION)
2009年
6期
1-4
,共4页
李崇%李志鹏%高正明%周英建%黄家琪
李崇%李誌鵬%高正明%週英建%黃傢琪
리숭%리지붕%고정명%주영건%황가기
撞击流反应器%微观混合%碘化物-碘酸盐反应体系%离集指数
撞擊流反應器%微觀混閤%碘化物-碘痠鹽反應體繫%離集指數
당격류반응기%미관혼합%전화물-전산염반응체계%리집지수
opposed-jet reactor%micromixing%iodide-iodate reaction system%segregation index
采用碘化物-碘酸盐平行竞争反应作为工作体系,对撞击流反应器内的微观混合特性进行了研究.考察了进料速率、氢离子浓度、撞击角度等因素对离集指数的影响规律,估算了撞击流反应器内的微观混合时间.结果表明:撞击角度在30°~180°范围以内,离集指数随着撞击角度的增加而下降;在实验范围流速以内(0.64~4.68m/s),随着溶液A流率的逐渐增大而减小.与常用的搅拌反应器相比,撞击流反应器具有优良的微观混合性能,更适合于快速反应过程.
採用碘化物-碘痠鹽平行競爭反應作為工作體繫,對撞擊流反應器內的微觀混閤特性進行瞭研究.攷察瞭進料速率、氫離子濃度、撞擊角度等因素對離集指數的影響規律,估算瞭撞擊流反應器內的微觀混閤時間.結果錶明:撞擊角度在30°~180°範圍以內,離集指數隨著撞擊角度的增加而下降;在實驗範圍流速以內(0.64~4.68m/s),隨著溶液A流率的逐漸增大而減小.與常用的攪拌反應器相比,撞擊流反應器具有優良的微觀混閤性能,更適閤于快速反應過程.
채용전화물-전산염평행경쟁반응작위공작체계,대당격류반응기내적미관혼합특성진행료연구.고찰료진료속솔、경리자농도、당격각도등인소대리집지수적영향규률,고산료당격류반응기내적미관혼합시간.결과표명:당격각도재30°~180°범위이내,리집지수수착당격각도적증가이하강;재실험범위류속이내(0.64~4.68m/s),수착용액A류솔적축점증대이감소.여상용적교반반응기상비,당격류반응기구유우량적미관혼합성능,경괄합우쾌속반응과정.
The micromixing characteristics of an opposed-jet reactor have been studied by using the parallel com-peting iodide-iodate reaction system. The effects of varying the feeding flow rate, concentration of sulfuric acid and impinging angles on the segregation index were investigated and the micromixing time was estimated. The experimental results show that the segregation index decreased with increasing impinging angle (30° - 180°) and feeding flow rate(0.64 - 4.68 m/s). It is shown that the opposed-jet reactor has a much better micromixing performance than traditional stirred reactors and is suitable for fast reaction systems.