CAJ | 학술논문

采用溶胶-凝胶法制备了CaTiO3:Zn纳米粒子,透射电镜图显示平均粒径为25 nm.Zn的掺杂位置对于陶瓷相组成和烧结特性有很大影响.Ca1-xZnxTiO3和CaTiO3+zZnO样品的Zn以Zn2TiO4相形式存在;而CaZnyTi1-yO3-δy=0.01)样品中的Zn进入Ti位形成固溶体,无明显的降温效果,当Zn量增至0.05和0.1时,出现ZnO相.ZnO和Zn2TiO4第二相的存在均能明显促进陶瓷烧结.CaTiO3:Zn超细粉体可在较低温度下致密烧结(≤1 250 ℃).1 250℃烧结的CaZnyTi1-yO3-δ(y=0.01)陶瓷具有较好的介电性能:介电常数ε=157,品质因数Q×f=6 819 GHz,谐振频率温度系数(τ)f=7.51×10-4℃-1.
채용용효-응효법제비료CaTiO3:Zn납미입자,투사전경도현시평균립경위25 nm.Zn적참잡위치대우도자상조성화소결특성유흔대영향.Ca1-xZnxTiO3화CaTiO3+zZnO양품적Zn이Zn2TiO4상형식존재;이CaZnyTi1-yO3-δy=0.01)양품중적Zn진입Ti위형성고용체,무명현적강온효과,당Zn량증지0.05화0.1시,출현ZnO상.ZnO화Zn2TiO4제이상적존재균능명현촉진도자소결.CaTiO3:Zn초세분체가재교저온도하치밀소결(≤1 250 ℃).1 250℃소결적CaZnyTi1-yO3-δ(y=0.01)도자구유교호적개전성능:개전상수ε=157,품질인수Q×f=6 819 GHz,해진빈솔온도계수(τ)f=7.51×10-4℃-1.
Nano-sizcd CaTiO3:Zn particles were synthesized by a sol-gel technique.The average particle size of the powder calculated from TEM micrograph is 25 nm.Zn substitution site has great influence on the phase composition and the sintering temperature of the ceramics.The added Zn exists as Zn2TiO4 phase for Ca1-xZnxTiO3 and CaTiO3+zZnO.However,for Ca (Zny,Ti1-y)O3-δ (y=0.01),Zn substitutes for Ti site and forms a solid solution,which has no obvious effect on sintering characteristics.When the y value is 0.05 and 0.1,ZnO phase is formed.The existence of ZnO or Zn2TiO4 phase can improve the sintering properties.The ultrafine CaTiO3∶Zn powders can be sintered at relatively lower temperatures (≤ 1250 ℃).CaZnyTi1-yO3-δ (y=0.01) sintered at 1 250 ℃ possesses a dielectric constant εrof 157,a Q×f value of 6819 GHz and a (τ)f value of 7.51×10-4 ℃-1.