广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2011年
20期
39-42
,共4页
乙醇%水蒸气重整%氢气
乙醇%水蒸氣重整%氫氣
을순%수증기중정%경기
ethanol%steam reforming%hydrogen
使用性能较优的10Co18La/Al2O3催化剂进行乙醇重整制氢反应,研究不同反应温度、反应空速的影响,结合反应机理进行探讨。结果表明:反应温度升高时,反应速率加快,乙醇转化率上升,氢气的选择性减小。反应空速增加时,反应速率加快,乙醇转化率下降,氢气的选择性增大。反应温度为500℃、反应空速为40 mL/(h.gcat.)时为最佳条件。
使用性能較優的10Co18La/Al2O3催化劑進行乙醇重整製氫反應,研究不同反應溫度、反應空速的影響,結閤反應機理進行探討。結果錶明:反應溫度升高時,反應速率加快,乙醇轉化率上升,氫氣的選擇性減小。反應空速增加時,反應速率加快,乙醇轉化率下降,氫氣的選擇性增大。反應溫度為500℃、反應空速為40 mL/(h.gcat.)時為最佳條件。
사용성능교우적10Co18La/Al2O3최화제진행을순중정제경반응,연구불동반응온도、반응공속적영향,결합반응궤리진행탐토。결과표명:반응온도승고시,반응속솔가쾌,을순전화솔상승,경기적선택성감소。반응공속증가시,반응속솔가쾌,을순전화솔하강,경기적선택성증대。반응온도위500℃、반응공속위40 mL/(h.gcat.)시위최가조건。
The catalyst 10Co18La/Al2O3 with a good performance was used in ethanol stream reforming reaction,and the different temperatures and reaction space velocities affecting the reaction were studied,combined with the reaction mechanism.The results showed when the reaction temperature rose,the reaction rate increased,the conversion rate of ethanol rose and,and the selectivity of H2 decreased.When the catalyst space velocity increased,the reaction rate increased,the conversion rate of ethanol declined,and the selectivity of H2 increased.The best condition was 500 ℃ and 40 mL/(h·gcat.).