一维化合物[Gd2(PDC)3(phen)(H2O)·H2O]n的合成、晶体结构及热性质
일유화합물[Gd2(PDC)3(phen)(H2O)·H2O]n적합성、정체결구급열성질
Synthesis,Crystal Structure and Thermogravimetric Analysis of A 1D Complex: [Gd2(PDC)3(phen)(H2O)·H2O]n
  • 万方数据
    无机化学学报 무궤화학학보
    JOURNAL OF INORGANIC CHEMISTRY
    2009年 5期 946-950 ,共5页

    梁青%李亚娟%宋会花%韩占刚%王继业

    량청%리아연%송회화%한점강%왕계업

    钆(Ⅲ)化合物%多羧基%晶体结构 釓(Ⅲ)化閤物%多羧基%晶體結構
    구(Ⅲ)화합물%다최기%정체결구
    gadolinium(Ⅲ) complex%multicarboxylate%crystal structure


    A one-dimensional complex, [Gd2(PDC)3(phen)(H2O) ? H2O]n (H2PDC=pyridine-3,4-dicarboxylic acid, phen =l,10-phenanthroline), has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TG analysis, and X-ray single-crystal structure analysis. Crystallographic data for the title complex:C33H21Gd2N5O14, Mr=l 026.05, Triclinic, space group P1, a=0.751 07(15) nm,b=1.256 5(3) nm, c=1.825 7(4) nm, α=70.80(3)°,β=79.00(3)°, γ=76.05(3)°, V=1.567 4(5) nm3, the final refinement gave R =0.022 4 and wR =0.047 5 for The current version does not support copying Cyrillic text to the Clipboard.The current version does not support copying Cyrillic text to the Clipboard.extended to a 3D supramolecular network through H-bonds interaction. CCDC: 671430.
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