载人航天
載人航天
재인항천
MANNED SPACEFLIGHT
2011年
6期
57-62
,共6页
刘炎%邢春英%陈国钦%王春雨%张强%武高辉
劉炎%邢春英%陳國欽%王春雨%張彊%武高輝
류염%형춘영%진국흠%왕춘우%장강%무고휘
Grf/6061A1复合材料%稀土转化膜%耐蚀性
Grf/6061A1複閤材料%稀土轉化膜%耐蝕性
Grf/6061A1복합재료%희토전화막%내식성
Grf/6061A1 composites%Rare Earth Conversion Coating%Corrosion Resistance
碳纤维增强铝基复合材料具有高比强度、高比模量等优异的力学性能,在航空航天领域有着极广泛的应用前景。然而,石墨纤维增强铝基复合材料在使用过程中极易发生多种形式的腐蚀破坏。利用SEM、EDS、全浸泡试验、极化曲线测试等手段,对Grf/6061A1复合材料表面不同成膜时间的稀土转化膜耐蚀性能进行了探讨。结果表明:稀土转化膜成膜完整时能有效阻碍氧和电子的迁移,从而使材料腐蚀电位φcorr上升,腐蚀电流密度icorr显著减小,点蚀敏感性下降,耐蚀性能显著提高;稀土膜成膜不完整时,不能有效阻碍氧和电子的迁移,相反由于成膜过程对材料的腐蚀作用,导致材料耐腐蚀性不佳甚至有所降低。
碳纖維增彊鋁基複閤材料具有高比彊度、高比模量等優異的力學性能,在航空航天領域有著極廣汎的應用前景。然而,石墨纖維增彊鋁基複閤材料在使用過程中極易髮生多種形式的腐蝕破壞。利用SEM、EDS、全浸泡試驗、極化麯線測試等手段,對Grf/6061A1複閤材料錶麵不同成膜時間的稀土轉化膜耐蝕性能進行瞭探討。結果錶明:稀土轉化膜成膜完整時能有效阻礙氧和電子的遷移,從而使材料腐蝕電位φcorr上升,腐蝕電流密度icorr顯著減小,點蝕敏感性下降,耐蝕性能顯著提高;稀土膜成膜不完整時,不能有效阻礙氧和電子的遷移,相反由于成膜過程對材料的腐蝕作用,導緻材料耐腐蝕性不佳甚至有所降低。
탄섬유증강려기복합재료구유고비강도、고비모량등우이적역학성능,재항공항천영역유착겁엄범적응용전경。연이,석묵섬유증강려기복합재료재사용과정중겁역발생다충형식적부식파배。이용SEM、EDS、전침포시험、겁화곡선측시등수단,대Grf/6061A1복합재료표면불동성막시간적희토전화막내식성능진행료탐토。결과표명:희토전화막성막완정시능유효조애양화전자적천이,종이사재료부식전위φcorr상승,부식전류밀도icorr현저감소,점식민감성하강,내식성능현저제고;희토막성막불완정시,불능유효조애양화전자적천이,상반유우성막과정대재료적부식작용,도치재료내부식성불가심지유소강저。
With the high specific strength and high specific modulus, carbon fibre reinforced aluminum matrix composites has a broad prospect of application in aerospace field. However, several forms of corrosion might happen in the course of use. In this paper, the morphology and composition of Ce conversion coating are studied by the scanning electronic microscope (SEM) and energy disperse spectroscopy (EDS). The corrosion resistance of the conversion coating is examined by immersion tests, polarization curves and electrochemical impedance spectroscopy. The results show that the complete Ce conversion coating could hinder the transfer of oxygen and electrons. Thereby, the corrosion potential φcorr of the specimens increases and the corrosion current density ieorr decreases. As a result, the sensitivity of pitting corrosion of the specimens reduces and the corrosion resistance increases. Due to the non-complete coating could not hinder the transfer of oxygen and electrons effectively and the corrosion behavior during coating formation, the corrosion resistance of the specimens decreases.