CAJ | 학술논문

以四氯邻苯二甲酸酐、尿素、Fecl2·4H2O为原料,合成了十六氯酞菁铁(FePcCl16),用元素分析、红外、紫外-可见光谱对产物进行了分析.FePcCl16具有较高的催化活性,对于大电流和低温放电尤其显著,并对放电电压滞后和放电时温升有较好的抑制作用.在常温和40 mA/cm2的电流密度下,相对于不含FePcCl16的ER34185型电池,含1.0g/L FePcCl16的电池的电压和容量分别提高了174 mV和830 mAh.
이사록린분이갑산항、뇨소、Fecl2·4H2O위원료,합성료십륙록태정철(FePcCl16),용원소분석、홍외、자외-가견광보대산물진행료분석.FePcCl16구유교고적최화활성,대우대전류화저온방전우기현저,병대방전전압체후화방전시온승유교호적억제작용.재상온화40 mA/cm2적전류밀도하,상대우불함FePcCl16적ER34185형전지,함1.0g/L FePcCl16적전지적전압화용량분별제고료174 mV화830 mAh.
Iron hexadecachlorinated phthalocyanine(FePcCl16)was synthesized by using tetrachloro-phthalic anhydride,urea and FeCl2·4H2O as raw materials．The products were analyzed by elemental analysis，IR and U V—vis spectra．FePcCl16 had higher catalytic activity,especially to heavy load and lower temperature discharge and had fine inhibition to voltage lag and temperature rise while discharge.At normal temperature with the current density of 40 mA/cm2,the increasing of voltage and capacity of the ER34185 type cell contained 1.0 g/L FePcCl16 comparing with that of FePcCl16-free cell was 174 mV and 830 mAh,respectively.