CAJ | 학술논문

建立了PSA分散固相萃取净化, 液相色谱柱后衍生荧光法测定蔬菜和水果中13种氨基甲酸酯农药的分析方法. 在建立的测定条件下, 13种氨基甲酸酯的含量与峰面积之间成线性关系, 相关系数大于0.994, 保留时间的相对标准偏差在0.03%～0.22%之间, 检测下限在2.00～2.28 μg/kg范围内. 西瓜、杏、茄子及胡萝卜中13种氨基甲酸酯的平均回收率在71.7%～110%之间, 相对标准偏差在0.68%～15%之间, 分析结果优于氨基柱固相萃取法.
건립료PSA분산고상췌취정화, 액상색보주후연생형광법측정소채화수과중13충안기갑산지농약적분석방법. 재건립적측정조건하, 13충안기갑산지적함량여봉면적지간성선성관계, 상관계수대우0.994, 보류시간적상대표준편차재0.03%～0.22%지간, 검측하한재2.00～2.28 μg/kg범위내. 서과、행、가자급호라복중13충안기갑산지적평균회수솔재71.7%～110%지간, 상대표준편차재0.68%～15%지간, 분석결과우우안기주고상췌취법.
Determination of thirteen carbamate pesticides residues in vegetables and fruits by HPLC with PSA dispersive solid-phase extraction cleanup and post-column derivatization fluorescence detection is developed. Under the optimal determination conditions, the detection limits of thirteen carbamate pesticides are in the range of 2.00～2.28 jug/kg. There is a good linear relationship in the content range of determination. The correlation coefficients of thirteen carbamate pesticides are more than 0.99. The relative standard deviations of retention time are in the range of 0.03%～0.22% . It is simpler in sample handling by PSA dispersive solid-phase extraction than by NH2 column solid-phase extraction. There are little interference in matrix, and high quality results are obtained. The spiked average recoveries of thirteen carbamate pesticide residues ranged from 71.7%～110% with RSDs of 0.68%～15% for watermelon, apricot, eggplant and carrot, The results are very satisfactory.