物理化学学报
物理化學學報
물이화학학보
ACTA PHYSICO-CHIMICA SINICA
2009年
1期
145-149
,共5页
溶胶-凝胶模板法%复合纳米管%磁性%铁电性
溶膠-凝膠模闆法%複閤納米管%磁性%鐵電性
용효-응효모판법%복합납미관%자성%철전성
Sol-gel temlplate method%Composite nanotube%Magnetic pooperty%Ferroelectricity
用溶胶-凝胶模板法合成了 CoFe2O4)/BaTiO3(CFO/BTO)复合纳米管,管的直径约为 100、200 和 300 nm,其长度约为100 μm.x射线衍射(xRD)和选区电子衍射(sAED)都显示复合纳米管中同时存在尖晶石相的CoFe2O4(CFO)和钙钛矿相的 BaTiO3(BTO),进一步的透射电子显微镜(TEM)研究证实合成的纳米复合物具有明显的管状结构.磁、电研究表明,该复合纳米管的磁性与纯 CFO 纳米管的磁性相当;而铁电性与纯BTO纳米管的铁电性相当.
用溶膠-凝膠模闆法閤成瞭 CoFe2O4)/BaTiO3(CFO/BTO)複閤納米管,管的直徑約為 100、200 和 300 nm,其長度約為100 μm.x射線衍射(xRD)和選區電子衍射(sAED)都顯示複閤納米管中同時存在尖晶石相的CoFe2O4(CFO)和鈣鈦礦相的 BaTiO3(BTO),進一步的透射電子顯微鏡(TEM)研究證實閤成的納米複閤物具有明顯的管狀結構.磁、電研究錶明,該複閤納米管的磁性與純 CFO 納米管的磁性相噹;而鐵電性與純BTO納米管的鐵電性相噹.
용용효-응효모판법합성료 CoFe2O4)/BaTiO3(CFO/BTO)복합납미관,관적직경약위 100、200 화 300 nm,기장도약위100 μm.x사선연사(xRD)화선구전자연사(sAED)도현시복합납미관중동시존재첨정석상적CoFe2O4(CFO)화개태광상적 BaTiO3(BTO),진일보적투사전자현미경(TEM)연구증실합성적납미복합물구유명현적관상결구.자、전연구표명,해복합납미관적자성여순 CFO 납미관적자성상당;이철전성여순BTO납미관적철전성상당.
Magnetoelectric CoFe2O4/BatiO3 composite nanotubes with lengths of about 100μm and diameters of about 100,200,and 300nm were prepared by a sol-gel template method. the coexistence of spinel CoFe2O4(CFO)and perovskite BaTio3(TIO)phases in the composite(CFO/BTO)nanotubes was revealed by X-ray diffraction(XRD)and selected area electron diffraction (SAED) patterns. Transmission eletron microcopy (TEM) confirmed that the nanocomposite had a tubular microstructure. magnetic properties of the CFO/BTO composite nanotubes were similar to the properties of pure CFO nanotubes. The ferroelectric properites of the composite nanotubes were equivalent to the ferroelectirc properties of pure BTO nanotubes.