化学反应工程与工艺
化學反應工程與工藝
화학반응공정여공예
CHEMICAL REACTION ENGINEERING AND TECHNOLOGY
2001年
2期
192-196
,共5页
聚醚%马来酸酐%缩合%破乳剂
聚醚%馬來痠酐%縮閤%破乳劑
취미%마래산항%축합%파유제
研究了催化剂量、回流温度、溶剂量对聚醚与马来酸酐缩合反应的影响，反应过程通过测量其出水量和酸值随时间的变化来表征，同时，辅之以FTIR表征。结果表明：不同情况下，其反应机理是不同的，总体而言，是一个酯化与醚化相互竞争的过程。通过研究确定了生产超稠油乳液破乳剂最佳工艺条件，得到的破乳剂使辽河超稠油脱水可达到<5%。
研究瞭催化劑量、迴流溫度、溶劑量對聚醚與馬來痠酐縮閤反應的影響，反應過程通過測量其齣水量和痠值隨時間的變化來錶徵，同時，輔之以FTIR錶徵。結果錶明：不同情況下，其反應機理是不同的，總體而言，是一箇酯化與醚化相互競爭的過程。通過研究確定瞭生產超稠油乳液破乳劑最佳工藝條件，得到的破乳劑使遼河超稠油脫水可達到<5%。
연구료최화제량、회류온도、용제량대취미여마래산항축합반응적영향，반응과정통과측량기출수량화산치수시간적변화래표정，동시，보지이FTIR표정。결과표명：불동정황하，기반응궤리시불동적，총체이언，시일개지화여미화상호경쟁적과정。통과연구학정료생산초주유유액파유제최가공예조건，득도적파유제사료하초주유탈수가체도<5%。
The effects of catalyst content, reflux temperature and solvent content on the condensation reaction between polyether and malaic anhydride were studied. The change of separated-off water volume and acidic value with time was monitored and FTIR was used to illustrate the process. It was shown that the reaction mechanism is variable under different experiment conditions, as a whole, the reaction is a competing process between esterification and etherification one another. By experimental study, the optimum technique conditions that produced super-viscous crude oil emulsion demulsifier, which could separate water with Liaohe super-voscous crude oil emulsion to <5%(wt)water content, was obtained.
