CAJ | 학술논문

为了考察溶胀作用对液化油煤浆黏度变化的影响作用,参照煤直接液化工艺条件,在四氢萘(THN)、N,N-二甲基甲酰胺(DMF)、液化起始溶剂(STA)和液化循环溶剂(REC)等不同有机溶剂中对胜利煤进行了溶胀行为研究.采用扫描电镜、孔隙比表面积分析仪、红外光谱仪等手段,研究了不同条件下胜利溶胀煤的表面性质变化.结果表明,胜利煤在极性溶剂N,N-二甲基甲酰胺中的溶胀度要大于在非极性溶剂四氢萘、起始溶剂和循环溶剂中的溶胀度;随着温度的升高,胜利煤的溶胀速率增大.溶胀后的胜利煤呈松散的云状结构,煤的形貌发生了一定程度变化;溶胀煤的孔径增大,比表面积减小.
위료고찰용창작용대액화유매장점도변화적영향작용,삼조매직접액화공예조건,재사경내(THN)、N,N-이갑기갑선알(DMF)、액화기시용제(STA)화액화순배용제(REC)등불동유궤용제중대성리매진행료용창행위연구.채용소묘전경、공극비표면적분석의、홍외광보의등수단,연구료불동조건하성리용창매적표면성질변화.결과표명,성리매재겁성용제N,N-이갑기갑선알중적용창도요대우재비겁성용제사경내、기시용제화순배용제중적용창도;수착온도적승고,성리매적용창속솔증대.용창후적성리매정송산적운상결구,매적형모발생료일정정도변화;용창매적공경증대,비표면적감소.
The swelling behaviors of Shengli coal in different solvents, such as THN, DMF, STA and REC, are investigated to observe the effects of solvent swelling on apparent viscosity of the coal slurries. Changes in the coal surface characteristics have been studied by using SEM, BET and FTIR. The results showed that the coal in different solvent has a different swelling ratio, and the effect of DMF on swelling is more obvious than that of THN, STA and REC. The swelling ratio increases with temperature, and the swelled coal presents an incompact sandwich structure having a lower specific surface area and a larger pore diameter.