中国环境科学
中國環境科學
중국배경과학
CHINA ENVIRONMENTAL SCIENCE
2010年
4期
448-452
,共5页
代伟%庄海棠%麻炳辉%韩敏敏%郑宇%陈庆渺
代偉%莊海棠%痳炳輝%韓敏敏%鄭宇%陳慶渺
대위%장해당%마병휘%한민민%정우%진경묘
MOF-199%噻吩%脱除
MOF-199%噻吩%脫除
MOF-199%새분%탈제
MOF-199%thiophene%removal
采用水热法合成新型多孔材料MOF-199,利用XRD、77K下N_2吸附等温线和SEM表征其结构.运用固定床吸附穿透曲线考察了模型燃油类型对MOF-199吸附分离噻吩的影响.结果表明,MOF-199在脂肪和芳香模型油中的饱和吸附容量分别为1.96wt%和1.85wt%,超过相关文献报道.MOF-199在含溶解水和纯混合模型油中噻吩硫的饱和吸附容量分别为2.15wt%和1.62wt%,脱硫吸附容量降低了25%.运用活性炭分层填装吸附柱技术可使MOF-199饱和吸附容量达到2.12wt%.
採用水熱法閤成新型多孔材料MOF-199,利用XRD、77K下N_2吸附等溫線和SEM錶徵其結構.運用固定床吸附穿透麯線攷察瞭模型燃油類型對MOF-199吸附分離噻吩的影響.結果錶明,MOF-199在脂肪和芳香模型油中的飽和吸附容量分彆為1.96wt%和1.85wt%,超過相關文獻報道.MOF-199在含溶解水和純混閤模型油中噻吩硫的飽和吸附容量分彆為2.15wt%和1.62wt%,脫硫吸附容量降低瞭25%.運用活性炭分層填裝吸附柱技術可使MOF-199飽和吸附容量達到2.12wt%.
채용수열법합성신형다공재료MOF-199,이용XRD、77K하N_2흡부등온선화SEM표정기결구.운용고정상흡부천투곡선고찰료모형연유류형대MOF-199흡부분리새분적영향.결과표명,MOF-199재지방화방향모형유중적포화흡부용량분별위1.96wt%화1.85wt%,초과상관문헌보도.MOF-199재함용해수화순혼합모형유중새분류적포화흡부용량분별위2.15wt%화1.62wt%,탈류흡부용량강저료25%.운용활성탄분층전장흡부주기술가사MOF-199포화흡부용량체도2.12wt%.
Novel porous material MOF-199 was synthesized by hydrothermal synthesis and characterized by XRD,SEM analyses and N_2 adsorption at 77 K.Types of simulated oils on adsorptive separation thiophene sulfur was stuied by fixed adsorption bed breakthrough curves.It was found that the saturation capacity of sulfur element for MOF-199 was 1.96wt% and 1.85wt%in the aliphatic and aromatic simulated oil,respectively,higher than those previously reported resuits.The saturation capacity of sulfur element for MOF-199 was 2.15wt%and 1.62wt%in mositure aliphatic and aromatic simulated oil mixture.However,when moisture existed,the capacity dropped to 1.62wt%,which decreased by 25% compared with dry oil mixture.Moreover,the saturation capacity of 2.12wt%can be obtained by laying actived carbon technique.