上海大学学报(英文版)
上海大學學報(英文版)
상해대학학보(영문판)
JOURNAL OF SHANGHAI UNIVERSITY (ENGLISH EDITION)
2008年
5期
466-470
,共5页
吕庆%赵丽树%王成立%张淑会%李福民%刘增勋
呂慶%趙麗樹%王成立%張淑會%李福民%劉增勛
려경%조려수%왕성립%장숙회%리복민%류증훈
CaO-SiO2-Al2O3-MgO-FeO slags%FeO activities%solid electrolyte cell%basicity%MgO content
Activities of FeO in CaO-SiO2-Al2O3-MgO-FeO slags were determined at 1673 K by electrochemical measurements of the solid electrolyte cell: Mo |Mo+MoO2[ZrO2(MgO)[Fe+(CaO-SiO2-Al2O3-MgO-FeO)+Ag|Fe. The influences of slag compositions and basicity on FeO activities were analyzed. The results reveal that, for slags of fixed (%CaO)/(%SiO2) ratio, MgO and Al2O3 content, there was an increase of FeO activities with increase of FeO content. For slags with constant {(%CaO)+ (%MgO)}/(%SiO2) ratio, fixed FeO and Al,2O3 content, FeO activities decreased when MgO content increased from 5% to 10%, and increased with the increase of MgO content when it was over 10%. The FeO activities increased when (%CaO)/(%SiO2) ratio changed from 1.03 to 1.30 in the slags of constant MgO, FeO and Al2O3 content.