催化学报
催化學報
최화학보
CHINESE JOURNAL OF CATALYSIS
2001年
2期
175-176
,共2页
苏文悦%陈亦琳%付贤智%魏可镁
囌文悅%陳亦琳%付賢智%魏可鎂
소문열%진역림%부현지%위가미
固体酸%二氧化钛%光催化剂%酸强度%溴代甲烷
固體痠%二氧化鈦%光催化劑%痠彊度%溴代甲烷
고체산%이양화태%광최화제%산강도%추대갑완
SO2-4/TiO2固体酸可用于光催化降解溴代甲烷,其光催化性能明显优于TiO2光催化剂.在相同反应条件下,SO2-4/TiO2的光催化活性比TiO2提高2~10倍.当H2SO4浸渍液浓度为1mol/L时,制得的SO2-4/TiO2酸性最强(H0<-12.14),具有超强酸性和最高的光催化活性.
SO2-4/TiO2固體痠可用于光催化降解溴代甲烷,其光催化性能明顯優于TiO2光催化劑.在相同反應條件下,SO2-4/TiO2的光催化活性比TiO2提高2~10倍.噹H2SO4浸漬液濃度為1mol/L時,製得的SO2-4/TiO2痠性最彊(H0<-12.14),具有超彊痠性和最高的光催化活性.
SO2-4/TiO2고체산가용우광최화강해추대갑완,기광최화성능명현우우TiO2광최화제.재상동반응조건하,SO2-4/TiO2적광최화활성비TiO2제고2~10배.당H2SO4침지액농도위1mol/L시,제득적SO2-4/TiO2산성최강(H0<-12.14),구유초강산성화최고적광최화활성.
SO2-4/TiO2 solid acid was used for photocatalytic degradation ofCH3Br, and its photocatal ytic activity is 2~10 times higher than that of TiO2 under the same reaction conditions. The SO2-4/TiO2 sample impregnated w ith H2SO4 solution (1 mol/L) is of superacidity (H0<-12.14), possessing the highest acid strength and the highest photocatalytic activity for degradation of CH3Br.