CAJ | 학술논문

钙钛矿型金属氧化物是一种优良的制备O2／CO2混合气体的载氧体，分别用柠檬酸溶胶凝胶法和EDTA-NH4-OH法制备了4种不同的钙钛矿型金属氧化物，采用X射线衍射分析表征不同钙钛矿金属氧化物的物相组成并在固定床实验台架上用气体分析仪对它们的与CO2的反应性能及其影响因素进行比较和研究。结果表明，新型BSCF载氧体的释氧性能最好，预处理时间及温度条件都会对新型钙钛矿型金属氧化物的释氧性能产生较大影响，且新鲜样品和循环后的样品的最佳反应条件有所不同。新鲜样品当预处理温度为800℃，预处理时间为1h时，BSCF释氧能力最佳，而第二次循环之后的最佳预处理温度在850℃左右。
개태광형금속양화물시일충우량적제비O2／CO2혼합기체적재양체，분별용저몽산용효응효법화EDTA-NH4-OH법제비료4충불동적개태광형금속양화물，채용X사선연사분석표정불동개태광금속양화물적물상조성병재고정상실험태가상용기체분석의대타문적여CO2적반응성능급기영향인소진행비교화연구。결과표명，신형BSCF재양체적석양성능최호，예처리시간급온도조건도회대신형개태광형금속양화물적석양성능산생교대영향，차신선양품화순배후적양품적최가반응조건유소불동。신선양품당예처리온도위800℃，예처리시간위1h시，BSCF석양능력최가，이제이차순배지후적최가예처리온도재850℃좌우。
Perovskite-type sorbents have been identified as great potential oxygen-carriers to produce oxygen enriched carbon dioxide stream. Sol-gel combustion synthesis method using different complexant, EDTA-NH4-OH and citric acid, was used for the preparation of four different pervoskite-type sorbents. The transient phase changes of the perovskite type oxides were characterized by X-ray diffraction （XRD） analysis, and the oxygen desorption ability as well as their influence factors were investigated in a fixed bed. The experimental results indicate that novel Ba0.5Sr0.5Co0.8Fe0.2O3-δ （BSCF） provides the best performance of oxygen desorption ability. Besides, both the pretreatment temperature and time have a great effect on the oxygen desorption ability of perovskite-type oxides. While a pretreatment condition of 800 ℃ for 1 h is optimal for the oxygen desorption of fresh BSCF, 850 ℃ is optimal for the BSCF after one cycle.