CAJ | 학술논문

以二水合钨酸钠与不同配体形成的络合物为催化剂,在相转移剂作用下,用30%的过氧化氢氧化环己烯合成己二酸。探讨了反应装置、催化剂用量、配体用量、相转移剂用量、反应时间、冷却时间对反应的影响。在优化条件下,即磷酸为配体,PEG600为相转移催化剂,220 mmol 30%H2O2氧化50 mmol环己烯,且n（Na2WO4.2H2O）∶n（H3PO4）∶n（环己烯）=1∶2∶20,常规回流3.0 h,己二酸的产率达67.4%。二水合钨酸钠和过氧化氢催化氧化体系重复使用5次后,己二酸的分离产率仍然较高。二水合钨酸钠/过氧化氢为一种绿色催化氧化体系,具有较好的发展前景。
이이수합오산납여불동배체형성적락합물위최화제,재상전이제작용하,용30%적과양화경양화배기희합성기이산。탐토료반응장치、최화제용량、배체용량、상전이제용량、반응시간、냉각시간대반응적영향。재우화조건하,즉린산위배체,PEG600위상전이최화제,220 mmol 30%H2O2양화50 mmol배기희,차n（Na2WO4.2H2O）∶n（H3PO4）∶n（배기희）=1∶2∶20,상규회류3.0 h,기이산적산솔체67.4%。이수합오산납화과양화경최화양화체계중복사용5차후,기이산적분리산솔잉연교고。이수합오산납/과양화경위일충록색최화양화체계,구유교호적발전전경。
Synthesis of adipic acid based on cyclohexene in phase transfer catalyst was investigated with 30% H2O2 as oxidant,complex compound formed by Na2WO4·2H2O as catalyst.The effects of catalyst dosage,ratio of Na2WO4·2H2O to H2O2,ligand dosage,phase transfer catalyst dosage and reaction time on reaction were studied.The results showed that the max yield of adipic acid was 67.4% when phosphoric acid was used as the ligand,PEG600 as the phase transfer catalyst and the molar ratio of Na2WO4·2H2O,H3PO4 and cyclohexene was 1∶2∶20.Although the aqueous solution of Na2WO4·2H2O and H2O2 was used for 5 times,the separation production rates were still high.The solution of Na2WO4·2H2O and H2O2,a kind of green catalyzed oxidation system,has good prospects for development..