合成化学
閤成化學
합성화학
CHINESE JOURNAL OF SYNTHETIC CHEMISTRY
2010年
2期
235-238
,共4页
何彦波%易春%曹迁永%邓阳生%高希存
何彥波%易春%曹遷永%鄧暘生%高希存
하언파%역춘%조천영%산양생%고희존
2-苯基吡啶%铱(Ⅲ)配合物%8-羟基喹啉衍生物%合成%光学性质
2-苯基吡啶%銥(Ⅲ)配閤物%8-羥基喹啉衍生物%閤成%光學性質
2-분기필정%의(Ⅲ)배합물%8-간기규람연생물%합성%광학성질
2-phenylpyridine%Iridium(Ⅲ) complex%8-hydroxyquinoline derivative%synthesis%optical property
以2-苯基吡啶为原料,经两步反应合成了3个8-羟基喹啉衍生物铱(Ⅲ)配合物(2a～2c),并研究和比较了2的光学性质和电化学行为.
以2-苯基吡啶為原料,經兩步反應閤成瞭3箇8-羥基喹啉衍生物銥(Ⅲ)配閤物(2a～2c),併研究和比較瞭2的光學性質和電化學行為.
이2-분기필정위원료,경량보반응합성료3개8-간기규람연생물의(Ⅲ)배합물(2a～2c),병연구화비교료2적광학성질화전화학행위.
Three Iridium(Ⅲ) complexes with the ligands of 5-chloro and 2-methyl substituted 8-hydroxyquinoline and 2-phenylpyridine were synthesized by a two-step reaction from 2-phenylpyridine. The structures were characterized by ~1HNMR and element analysis. Their UV-Vis absorption, fluorescence emission and electrochemical behaviors were studied and compared.
