燃料化学学报
燃料化學學報
연료화학학보
JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY
2009年
6期
679-683
,共5页
杜谋涛%黄勇成%尚上%王鹏%王丽%郭和军
杜謀濤%黃勇成%尚上%王鵬%王麗%郭和軍
두모도%황용성%상상%왕붕%왕려%곽화군
柴油%生物质油%乳化剂%HLB值%理化性质
柴油%生物質油%乳化劑%HLB值%理化性質
시유%생물질유%유화제%HLB치%이화성질
diesel%bio-oil%emulsion%hydrophilic and lipophilic balance value%physicochemical properties
采用超声波乳化法制备柴油-生物质油乳化燃料,并研究了乳化燃料所需乳化剂的最佳亲水亲油平衡(HLB)值以及乳化条件对乳化燃料稳定性的影响,测定了乳化燃料的密度、黏度、闭口闪点、烟点、凝点和总热值等理化性质.结果表明,柴油-生物质油乳化燃料乳化剂的最佳HLB值为5.5~6.2;当乳化温度为50℃~60℃、单位容积输入功为180J/mL~300J/mL时,乳化燃料的稳定性最好;乳化燃料的密度、黏度、闪点和烟点随生物质油比例的增加而增大,而凝点和总热值则随生物质油比例的增加而降低.
採用超聲波乳化法製備柴油-生物質油乳化燃料,併研究瞭乳化燃料所需乳化劑的最佳親水親油平衡(HLB)值以及乳化條件對乳化燃料穩定性的影響,測定瞭乳化燃料的密度、黏度、閉口閃點、煙點、凝點和總熱值等理化性質.結果錶明,柴油-生物質油乳化燃料乳化劑的最佳HLB值為5.5~6.2;噹乳化溫度為50℃~60℃、單位容積輸入功為180J/mL~300J/mL時,乳化燃料的穩定性最好;乳化燃料的密度、黏度、閃點和煙點隨生物質油比例的增加而增大,而凝點和總熱值則隨生物質油比例的增加而降低.
채용초성파유화법제비시유-생물질유유화연료,병연구료유화연료소수유화제적최가친수친유평형(HLB)치이급유화조건대유화연료은정성적영향,측정료유화연료적밀도、점도、폐구섬점、연점、응점화총열치등이화성질.결과표명,시유-생물질유유화연료유화제적최가HLB치위5.5~6.2;당유화온도위50℃~60℃、단위용적수입공위180J/mL~300J/mL시,유화연료적은정성최호;유화연료적밀도、점도、섬점화연점수생물질유비례적증가이증대,이응점화총열치칙수생물질유비례적증가이강저.
Bio-oil produced from biomass by fast pyrolysis is mainly composed of oxygenated organics and contains high content of water, which makes it unsuitable for direct use as fuel. By developing emulsions from diesel and bio-oil, however, the bio-oil can then be used in compression ignition engines. In this work, the emulsions from diesel and bio-oil are produced by using ultrasonic emulsification method. The physicochemical properties of the emulsions were measured, including density, viscosity, flash point, smoke point, freezing point, and gross heating value. The optimum hydrophilic and lipophilic balance (HLB) value of the emulsifier and the influence of emulsification conditions on the emulsion stability were investigated. The results show that the optimum HLB value of the emulsifier for the emulsification of diesel and bio-oil is about 5.5~6.2;the most stable emulsions are then obtained when the emulsification is conducted at 50℃~60℃ and with the input work of 180J/mL~300J/mL. With the increase of bio-oil content in the emulsions, the density, viscosity, flash point and smoke point of the emulsions are increased, while their freezing point and gross heating value are decreased.