广东化工
廣東化工
엄동화공
GUANGDONG CHEMICAL INDUSTRY
2010年
10期
6-7,26
,共3页
明胶%壳聚糖%PVA-SbQ%光交联%膜
明膠%殼聚糖%PVA-SbQ%光交聯%膜
명효%각취당%PVA-SbQ%광교련%막
gel%CS%PVA-SbQ: photocross-link%membrane
本实验用以聚乙烯醇-苯乙烯基吡啶盐的缩合物(PVA—SbQ)为光敏剂,运用紫外光辐照法以制备交联明胶-壳聚糖共混膜。用傅立叶红外、X-射线衍射方法对膜的结构进行表征,并对膜的力学性能、吸湿率、透光率性能进行研究。研究表明:PVA—SbQ分子与明胶、壳聚糖分子间存在氢键作用,光交联后,共混膜形成网状结构,有效地改善了共混膜的力学性能、吸湿性和紫外屏蔽性能等。
本實驗用以聚乙烯醇-苯乙烯基吡啶鹽的縮閤物(PVA—SbQ)為光敏劑,運用紫外光輻照法以製備交聯明膠-殼聚糖共混膜。用傅立葉紅外、X-射線衍射方法對膜的結構進行錶徵,併對膜的力學性能、吸濕率、透光率性能進行研究。研究錶明:PVA—SbQ分子與明膠、殼聚糖分子間存在氫鍵作用,光交聯後,共混膜形成網狀結構,有效地改善瞭共混膜的力學性能、吸濕性和紫外屏蔽性能等。
본실험용이취을희순-분을희기필정염적축합물(PVA—SbQ)위광민제,운용자외광복조법이제비교련명효-각취당공혼막。용부립협홍외、X-사선연사방법대막적결구진행표정,병대막적역학성능、흡습솔、투광솔성능진행연구。연구표명:PVA—SbQ분자여명효、각취당분자간존재경건작용,광교련후,공혼막형성망상결구,유효지개선료공혼막적역학성능、흡습성화자외병폐성능등。
In the experiment, photocross-linked gelatin-chitosan blend membrane was prepared by mixing the solutions of gelatin, chitosan and PVA-SbQ. Its structure was examined by means of FT-IR and XRD. The properties of membrane, such as mechanical property, hygroscopicity and light transmittance had been studied. The results show that: improved properties of the membrane such as mechanical property, hygroscopicity and UV screen property are due to some hydrogen bonding interaction between gelatin, chitosan and PVA-SbQ in the blend membrane and network of exposed membrane.