中国化学工程学报(英文版)
中國化學工程學報(英文版)
중국화학공정학보(영문판)
CHINESE JOURNAL OF CHEMICAL ENGINEERING
2002年
4期
454-458
,共5页
刘迪霞%李浩然%邓东顺%韩世钧
劉迪霞%李浩然%鄧東順%韓世鈞
류적하%리호연%산동순%한세균
excess molar volume%binary mixture%2-methyl-3-buten-2-ol%1-alcohol%apparent molar volume
Excess molar volumes (VEm) of binary mixtures of 2-methyl-3-buten-2-ol [CH3C(OH)(CH3)CHCH2]with four 1-alcohols: methanol, ethanol, 1-propanol and 1-butanol at 298.15 K and atmospheric pressure are derived from density measurements with a vibrating-tube densimeter. All the excess volumes are negative in the systems over the entire composition range. The results are correlated with the Redlich-Kister equation. The effects of chain length of 1-alcohols on VmE are discussed. The apparent molar volumes of 2-methyl-3-buten-2-ol and 1-alcohols are calculated respectively.