CAJ | 학술논문

用胡椒醛、乙酰乙酸乙酯和醋酸铵在微波辐射下干反应得4-胡椒基-2,6-二甲基-3,5-乙氧羰基-1,4-二氢吡啶 1(C20H23NO6),4-胡椒基-2,6-二甲基-3,5-乙氧羰基-1,4-二氢吡啶在NDC (烟酸三氧化铬) 存在下经微波辐射得到4-胡椒基-2,6-二甲基-3,5-乙氧羰基吡啶 2 (C20H21NO6).产物的结构通过单晶X-射线衍射法确定, 1 属单斜晶系, 空间群P21/c, a = 14.864(3), b = 9.830(1), c = 14.517(3), α = 115.25(1)A, V = 1918.6(6)A3, Z = 4, Mr = 373.39, Dc = 1.293g/cm3, μ(MoKα)=0.096mm-1, F(000)=792.最终的偏离因子为R = 0.0496, wR = 0.1368.2 属三斜晶系,空间群Pī, a = 8.915(1), b = 10.575(1), c = 11.904(1)A,α = 102.19(1)°,V = 109.43(1)A,γ=108.94(1)°, V=934.79(16) A3, Z = 2, Mr = 371.38, Dc = 1.319g/cm3 , μ(MoKα = 0.098mm-1, F(000) = 392.最终的偏离因子为R=0.0412, wR=0.1011.1 的二氢吡啶环为信封式结构, 2的吡啶环为平面结构.
용호초철、을선을산을지화작산안재미파복사하간반응득4-호초기-2,6-이갑기-3,5-을양탄기-1,4-이경필정 1(C20H23NO6),4-호초기-2,6-이갑기-3,5-을양탄기-1,4-이경필정재NDC (연산삼양화락) 존재하경미파복사득도4-호초기-2,6-이갑기-3,5-을양탄기필정 2 (C20H21NO6).산물적결구통과단정X-사선연사법학정, 1 속단사정계, 공간군P21/c, a = 14.864(3), b = 9.830(1), c = 14.517(3), α = 115.25(1)A, V = 1918.6(6)A3, Z = 4, Mr = 373.39, Dc = 1.293g/cm3, μ(MoKα)=0.096mm-1, F(000)=792.최종적편리인자위R = 0.0496, wR = 0.1368.2 속삼사정계,공간군Pī, a = 8.915(1), b = 10.575(1), c = 11.904(1)A,α = 102.19(1)°,V = 109.43(1)A,γ=108.94(1)°, V=934.79(16) A3, Z = 2, Mr = 371.38, Dc = 1.319g/cm3 , μ(MoKα = 0.098mm-1, F(000) = 392.최종적편리인자위R=0.0412, wR=0.1011.1 적이경필정배위신봉식결구, 2적필정배위평면결구.