发光学报
髮光學報
발광학보
CHINESE JOURNAL OF LUMINESCENCE
2010年
2期
189-193
,共5页
ZnO%薄膜%气相输运%水蒸气
ZnO%薄膜%氣相輸運%水蒸氣
ZnO%박막%기상수운%수증기
ZnO%thin film%vapor transport%water vapor
运用气相输运技术在不同的衬底上制备ZnO薄膜,同时对这些ZnO薄膜的表面形貌、晶体结构和光学特性进行表征.在扫描电子显微镜图像上可以看到,相比没有镀金的Si衬底,ZnO纳米颗粒在镀金的Si衬底上的生长尺寸较大.X射线衍射测试结果表明,在Si(111)和Si(100)衬底上生长的ZnO薄膜显示出不同的六角纤锌矿结构的衍射峰,但没有出现立方闪锌矿ZnO结构的衍射峰.在镀金的Si衬底上,ZnO薄膜生长取向主要为c轴方向.此外,所有ZnO样品的光致发光谱上均只出现一个狭窄且强的紫外峰,约在389 nm(3.19 eV)波长处.
運用氣相輸運技術在不同的襯底上製備ZnO薄膜,同時對這些ZnO薄膜的錶麵形貌、晶體結構和光學特性進行錶徵.在掃描電子顯微鏡圖像上可以看到,相比沒有鍍金的Si襯底,ZnO納米顆粒在鍍金的Si襯底上的生長呎吋較大.X射線衍射測試結果錶明,在Si(111)和Si(100)襯底上生長的ZnO薄膜顯示齣不同的六角纖鋅礦結構的衍射峰,但沒有齣現立方閃鋅礦ZnO結構的衍射峰.在鍍金的Si襯底上,ZnO薄膜生長取嚮主要為c軸方嚮.此外,所有ZnO樣品的光緻髮光譜上均隻齣現一箇狹窄且彊的紫外峰,約在389 nm(3.19 eV)波長處.
운용기상수운기술재불동적츤저상제비ZnO박막,동시대저사ZnO박막적표면형모、정체결구화광학특성진행표정.재소묘전자현미경도상상가이간도,상비몰유도금적Si츤저,ZnO납미과립재도금적Si츤저상적생장척촌교대.X사선연사측시결과표명,재Si(111)화Si(100)츤저상생장적ZnO박막현시출불동적륙각섬자광결구적연사봉,단몰유출현립방섬자광ZnO결구적연사봉.재도금적Si츤저상,ZnO박막생장취향주요위c축방향.차외,소유ZnO양품적광치발광보상균지출현일개협착차강적자외봉,약재389 nm(3.19 eV)파장처.
The characterizations of surface morphologies, crystal structures, and optical properties of the ZnO films prepared by a vapour-phase technique on different substrates were performed in this study. Scanning electron micro-scopy (SEM) data showed that larger ZnO particles are formed on the Au-covered Si substrates than those on Si substrates. X-ray diffraction (XRD) results indicated that hexagonal wurtzite ZnO films are grown on both Si(111) and Si(100) substrates though they present different diffraction peaks with hexagonal wurtzite structure, while appears no sphalerite structure. The ZnO films prepared on Au-coated Si substrates prefer to grow along with c-axis orientation. The PL spectra reveal only a narrow strong UV emission peak at about 389 nm (3.19 eV) in all the ZnO samples.