无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2009年
4期
738-741
,共4页
高东昭%赵为为%陈毅雯%孙亚秋
高東昭%趙為為%陳毅雯%孫亞鞦
고동소%조위위%진의문%손아추
锌配合物%氮氧自由基%晶体结构%磁行为
鋅配閤物%氮氧自由基%晶體結構%磁行為
자배합물%담양자유기%정체결구%자행위
Zn(Ⅱ)complex%nitronyl nitroxide radical%crystal structure%magnetic behavior
A Zn(Ⅱ)complex with nitronyl nitroxide radicals[Zn(NIT3Py)2Cl2](1)(NIT3Py=2-(3'-pyridinyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)has been synthesized and structurally characterized by X-ray diffraction crystal structure determination method.The complex has a mononuclear-metal structure in which each Zn(Ⅱ)ion adopts a distorted tetrahedral geometry and is coordinated by two Cl-anions and two pyndyl-N atoms from two NIT3Py radical ligands.The magnetic measurements show the weak antiferromagnetic interaction between the nitroxide radicals through the diamagnetic Zn(Ⅱ)ion.CCDC:292363.
