塑料
塑料
소료
PLASTICS
2009年
6期
47-49
,共3页
温时宝%张如根%孙雪丽%范海军%吴其晔
溫時寶%張如根%孫雪麗%範海軍%吳其曄
온시보%장여근%손설려%범해군%오기엽
原位聚合%聚苯胺%聚酰亚胺%电导率%复合膜
原位聚閤%聚苯胺%聚酰亞胺%電導率%複閤膜
원위취합%취분알%취선아알%전도솔%복합막
in-situ polymerization%po]yani]ine%po]yimide%conductivity%compound film
以聚酰亚胺(PI)膜为基体,采用分散聚合原位沉积方法制得聚苯胺/聚酰亚胺/聚苯胺(PANI/PL/PANI)三层复合膜.复合膜表面PANI层外观质量优异,电导率达10~0S/cm.实验结果表明:加入高浓度空间稳定剂(聚乙烯吡咯烷酮,PVP)、调整氧化剂(过硫酸铵,APS)和介质酸(盐酸)的用量可制得表面质量和电导率高的复合膜.较适宜的反应条件为稳定剂质量浓度4%,APS与苯胺(An)的物质的量比为2:4,盐酸浓度为0.5 mol/L.
以聚酰亞胺(PI)膜為基體,採用分散聚閤原位沉積方法製得聚苯胺/聚酰亞胺/聚苯胺(PANI/PL/PANI)三層複閤膜.複閤膜錶麵PANI層外觀質量優異,電導率達10~0S/cm.實驗結果錶明:加入高濃度空間穩定劑(聚乙烯吡咯烷酮,PVP)、調整氧化劑(過硫痠銨,APS)和介質痠(鹽痠)的用量可製得錶麵質量和電導率高的複閤膜.較適宜的反應條件為穩定劑質量濃度4%,APS與苯胺(An)的物質的量比為2:4,鹽痠濃度為0.5 mol/L.
이취선아알(PI)막위기체,채용분산취합원위침적방법제득취분알/취선아알/취분알(PANI/PL/PANI)삼층복합막.복합막표면PANI층외관질량우이,전도솔체10~0S/cm.실험결과표명:가입고농도공간은정제(취을희필각완동,PVP)、조정양화제(과류산안,APS)화개질산(염산)적용량가제득표면질량화전도솔고적복합막.교괄의적반응조건위은정제질량농도4%,APS여분알(An)적물질적량비위2:4,염산농도위0.5 mol/L.
Polyaniline/polyamide/polyaniline (PANI/PL/PANI) compound films were prepared through an in-situ deposition method on PI matrix in a dispersion polymerization system. The PANI layer of compound film had a high conductivity (10~0 S/cm) and an excellent appearance quality. In reaction system,the compound film was improved by adding high concentration of stabilizer(polyvinylpyrrolidone, PVP) ,and controlling a mount of oxidant and acid contribute. The typical reaction conditions were as follews :concentration of PVP was 4 % ,ratio of ammonium persulfate and aniline was 2:4 and HCI concentration was 0. 5 mol/L.