一种镧系-过渡金属二维氰桥配合物[Nd(DMSO)2(H2O)2][Ni(CN)4]Cl(DMSO=二甲亚砜)的合成和晶体结构
일충란계-과도금속이유청교배합물[Nd(DMSO)2(H2O)2][Ni(CN)4]Cl(DMSO=이갑아풍)적합성화정체결구
Synthesis and Crystal Structure of a Cyano-Bridged Lanthanide-Transition-Metal Complex [Nd(DMSO)2(H2O)2][Ni(CN)4]Cl (DMSO=Dimethylsulfoxide) with Two-dimensional Gridding Molecule Structure
  • 万方数据
    无机化学学报 무궤화학학보
    JOURNAL OF INORGANIC CHEMISTRY
    2005年 7期 1055-1059 ,共5页

    梁淑惠%车云霞%郑吉民

    량숙혜%차운하%정길민

    氰桥配合物%镧系-过渡金属配合物%二甲亚砜 氰橋配閤物%鑭繫-過渡金屬配閤物%二甲亞砜
    청교배합물%란계-과도금속배합물%이갑아풍
    cyano-bridged complex%lanthanide-transition metal complex%DMSO


    The cyano-bridged bimetallic complex [Nd(DMSO)2(H2O)2][Ni(CN)4]Cl with two-dimensional gridding molecule structure was synthesized and characterized. In the complex all four cyano groups of unit Ni(CN)42- are bound to Nd3+ ions. The crystal data for the title complex: monoclinic, space group P21/c, a=0.780 0(3) nm,b=1.5097(6) nm, c=1.683 2(6) nm, β=115.231(14)°, Z=4, μ=4.311 mm-1, final R1=0.020 9, wR2=0.045 4. CCDC:272214.
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