稀有金属材料与工程
稀有金屬材料與工程
희유금속재료여공정
RARE METAL MATERIALS AND ENGINEERNG
2009年
z2期
621-623
,共3页
潘笑风%廖家轩%王洪全%张佳%傅向军%魏雄邦
潘笑風%廖傢軒%王洪全%張佳%傅嚮軍%魏雄邦
반소풍%료가헌%왕홍전%장가%부향군%위웅방
掺杂%钛酸锶钡薄膜%钇%溶胶-凝胶法%介电性能
摻雜%鈦痠鍶鋇薄膜%釔%溶膠-凝膠法%介電性能
참잡%태산송패박막%을%용효-응효법%개전성능
doping%barium strontium titanate film%yttrium (Y)%sol-gel%dielectric properties
用改进溶胶-凝胶法在Pt/Ti/SiO_2/Si上制备了钇(Y)掺杂Ba_0.6Sr_0.4TiO_3 (BST)薄膜,研究了Y掺杂对BST薄膜表面结构和介电性能的影响.XPS结果表明,Y掺杂有利于薄膜钙钛矿结构的形成,但对氧空位没有明显的抑制作用.SEM和AFM结果表明,Y掺杂能缓解薄膜应力、减少薄膜裂纹、细化晶粒,进而改善薄膜的表面结构.在进行Y掺杂后,薄膜的介电性能得到明显提高,40 V外加电压下的介电调谐率大于40%及零偏压下介电损耗为0.0210,优化因子大于20.
用改進溶膠-凝膠法在Pt/Ti/SiO_2/Si上製備瞭釔(Y)摻雜Ba_0.6Sr_0.4TiO_3 (BST)薄膜,研究瞭Y摻雜對BST薄膜錶麵結構和介電性能的影響.XPS結果錶明,Y摻雜有利于薄膜鈣鈦礦結構的形成,但對氧空位沒有明顯的抑製作用.SEM和AFM結果錶明,Y摻雜能緩解薄膜應力、減少薄膜裂紋、細化晶粒,進而改善薄膜的錶麵結構.在進行Y摻雜後,薄膜的介電性能得到明顯提高,40 V外加電壓下的介電調諧率大于40%及零偏壓下介電損耗為0.0210,優化因子大于20.
용개진용효-응효법재Pt/Ti/SiO_2/Si상제비료을(Y)참잡Ba_0.6Sr_0.4TiO_3 (BST)박막,연구료Y참잡대BST박막표면결구화개전성능적영향.XPS결과표명,Y참잡유리우박막개태광결구적형성,단대양공위몰유명현적억제작용.SEM화AFM결과표명,Y참잡능완해박막응력、감소박막렬문、세화정립,진이개선박막적표면결구.재진행Y참잡후,박막적개전성능득도명현제고,40 V외가전압하적개전조해솔대우40%급령편압하개전손모위0.0210,우화인자대우20.
Yttrium (Y)-doped Ba_0.6Sr_0.4TiO_3 (BST) films were prepared on Pt/Ti/SiO_2/Si by improved Sol-gel method. The surface structure and dielectric properties of the BST films were investigated. X-ray photoelectron spectrum shows that the surface structures of Y-doped BST films are composed of perovskite structure and non-perovskite structure, and Y doping is helpful to increase the amount of perovskite structure, but is not so obvious to reduce oxygen vacancies. Scanning electron microscope and atomic force microscope exhibit that Y doping is beneficial to reduce stress and cracks, make crystal size smaller, and thus improve film surface structure. Also, Y doping markedly improves film dielectric properties with more than 40% tunability at 40 V, about 0.0210 dielectric loss (tand) at zero bias and hence merit value more than 20 figure.