襄樊学院学报
襄樊學院學報
양번학원학보
JOURNAL OF XIANGFAN UNIVERSITY
2011年
11期
22-25
,共4页
三芳胺%咔唑基%空穴传输材料
三芳胺%咔唑基%空穴傳輸材料
삼방알%잡서기%공혈전수재료
Tertiary aromatic amine%Carbazolyl%Hole-transporting material
利用咔唑衍生物和三芳胺类化合物合成了一种新型咔唑基三芳胺空穴传输材料,通过红外光谱、核磁共振氢谱等测试手段对合成产物的组成和结构进行了分析鉴定.测定了紫外-可见吸收光谱、荧光发射光谱,并利用循环伏安法结合紫外-可见光谱测定了其HOMO能级和LUMO能级.结果表明该化合物具有优良的空穴传输性能.
利用咔唑衍生物和三芳胺類化閤物閤成瞭一種新型咔唑基三芳胺空穴傳輸材料,通過紅外光譜、覈磁共振氫譜等測試手段對閤成產物的組成和結構進行瞭分析鑒定.測定瞭紫外-可見吸收光譜、熒光髮射光譜,併利用循環伏安法結閤紫外-可見光譜測定瞭其HOMO能級和LUMO能級.結果錶明該化閤物具有優良的空穴傳輸性能.
이용잡서연생물화삼방알류화합물합성료일충신형잡서기삼방알공혈전수재료,통과홍외광보、핵자공진경보등측시수단대합성산물적조성화결구진행료분석감정.측정료자외-가견흡수광보、형광발사광보,병이용순배복안법결합자외-가견광보측정료기HOMO능급화LUMO능급.결과표명해화합물구유우량적공혈전수성능.
A new V type hole-transporting material including carbazole and tertiary aromatic amine is synthesized.The structure was confirmed by IR and HNMR,etc.Its physical properties were studied by UV-Vis and fluorescence-emission.The HOMO energy levels of these compounds were obtained from cyclic voltammetry,The LUMO energy levels were obtained from the HOMO energy levels together with the UV-Vis spectrometry.The results show that the compounds have excellent hole-transporting performance.
