CAJ | 학술논문

文章用2-（5-甲基-1，3，4-噻二唑）-硫乙酸配体和1，2-顺（4-吡啶）乙烷配体用水热法合成了一个镍配合物{[Ni（bpe）（Hmtyaa）：（H：0）：]}lq（1）（Hmtyaa=2-（5-甲基-1，3，4-噻二唑）-硫乙酸；bpe=1，2-顺（4-吡啶）乙烷，用X-射线单晶衍射仪测定了配合物的单晶结构，并对它进行了元素分析、红外光谱、热重和粉末X-射线衍射表征．配合物1属于单斜晶系C2／c空间群．X-射线单晶结构分析表明配合物1中镍原子采取六配位扭曲的八面体配位模式．bpe配体采取双齿桥连模式将临近的镍原子连接成一维链状结构，在配合物1中配位水与羧基氧以及配体中的氮原子之间的氢键作用将链状结构连成三维网状结构．
문장용2-（5-갑기-1，3，4-새이서）-류을산배체화1，2-순（4-필정）을완배체용수열법합성료일개얼배합물{[Ni（bpe）（Hmtyaa）：（H：0）：]}lq（1）（Hmtyaa=2-（5-갑기-1，3，4-새이서）-류을산；bpe=1，2-순（4-필정）을완，용X-사선단정연사의측정료배합물적단정결구，병대타진행료원소분석、홍외광보、열중화분말X-사선연사표정．배합물1속우단사정계C2／c공간군．X-사선단정결구분석표명배합물1중얼원자채취륙배위뉴곡적팔면체배위모식．bpe배체채취쌍치교련모식장림근적얼원자련접성일유련상결구，재배합물1중배위수여최기양이급배체중적담원자지간적경건작용장련상결구련성삼유망상결구．
One nickel coordination compound / [ Ni（bpe）（Hmtyaa）2 （ H2O）2 ] n （ 1 ） containing ligands 2-（5- methyl-1,3,4-thiadiazol-2-yhhio） acetic acid and 4-（2-（pyridine-4-yl） ethyl） pyridine has been hydrothermally synthesized, and it is structurally characterized by single-crystal X-ray diffraction, and then by elemental analysis, FTIR spectra, thermal analysis and powder X-ray diffraction. Coordination compound 1 is crystallized in the mono- clinic, space group C2/. Single-crystal X-ray diffraction analysis indicates that each nickel atom is six-coordinated and exhibits a distorted octahedral geometry. Bpe ligands adopts bidentate bridging mode and links the adjacent nickel atoms, resulting in a one-dimensional chain structure. The hydrogen bonds between coordinated water and carboxylic oxygen as well as the nitrogen atoms of ligands are connected with the chain structure to form a 3-D structure network.