材料导报
材料導報
재료도보
MATERIALS REVIEW
2009年
14期
117-120
,共4页
张成责%孙春红%张晓静%贾天刚%李亚东
張成責%孫春紅%張曉靜%賈天剛%李亞東
장성책%손춘홍%장효정%가천강%리아동
PA 6/POE/粘土纳米复合材料%力学性能%储能模量%热稳定性
PA 6/POE/粘土納米複閤材料%力學性能%儲能模量%熱穩定性
PA 6/POE/점토납미복합재료%역학성능%저능모량%열은정성
PA 6/POE/clay nanocomposites%mechanical performance%storage modulus%thermal stability
采用熔融方法制备了PA 6/POE/粘土纳米复合材料.PA 6/POE/粘土纳米复合材料具有良好的力学性能,其缺口冲击强度比PA 6有显著提高.研究结果表明,有机粘土剥离于PA 6基体中,POE相以岛状结构均匀分散于PA 6基体中;PA 6/POE/粘土纳米复合材料的储能模量比PA 6的低,并且随着有机粘土含量的增加而降低.PA 6/POE/粘土纳米复合材料的玻璃化转变温度(Tg)随着粘土含量的增加而升高,具有良好的热稳定性.
採用鎔融方法製備瞭PA 6/POE/粘土納米複閤材料.PA 6/POE/粘土納米複閤材料具有良好的力學性能,其缺口遲擊彊度比PA 6有顯著提高.研究結果錶明,有機粘土剝離于PA 6基體中,POE相以島狀結構均勻分散于PA 6基體中;PA 6/POE/粘土納米複閤材料的儲能模量比PA 6的低,併且隨著有機粘土含量的增加而降低.PA 6/POE/粘土納米複閤材料的玻璃化轉變溫度(Tg)隨著粘土含量的增加而升高,具有良好的熱穩定性.
채용용융방법제비료PA 6/POE/점토납미복합재료.PA 6/POE/점토납미복합재료구유량호적역학성능,기결구충격강도비PA 6유현저제고.연구결과표명,유궤점토박리우PA 6기체중,POE상이도상결구균균분산우PA 6기체중;PA 6/POE/점토납미복합재료적저능모량비PA 6적저,병차수착유궤점토함량적증가이강저.PA 6/POE/점토납미복합재료적파리화전변온도(Tg)수착점토함량적증가이승고,구유량호적열은정성.
Nylon 6/ployolefin elastomer/clay nanocomposites are prepared by melt blending. Mechanical testing results show that PA 6/POE/clay nanocomposites have better mechanical properties, especially, the impact strength of nanocomposites increases significantly. Organoclay plates are completely exfoliated in PA 6 matrix. From the SEM results, island POE domain homogeneously disperses in PA 6/POE/clay nanocomposites. Storage modulus of nanocomposites is lower than that of PA 6 and decreases with content of clay increasing. Glass transition temperature of nanocomposites is higher than that of PA 6 and increases with content of clay increasing. The nanocomposites have good thermal stability.