过程工程学报
過程工程學報
과정공정학보
The Chinese Journal of Process Engineering
2009年
6期
1237-1241
,共5页
王平%赵建青%蒋智杰%刘运春%刘述梅
王平%趙建青%蔣智傑%劉運春%劉述梅
왕평%조건청%장지걸%류운춘%류술매
SiO_2%聚碳酸酯%表面改性%力学性能%流变性能
SiO_2%聚碳痠酯%錶麵改性%力學性能%流變性能
SiO_2%취탄산지%표면개성%역학성능%류변성능
SiO_2%polycarbonate%surface modification%mechanical performance%rheological property
采用SiO_2纳米粒子填充改性聚碳酸酯(PC),为使无机纳米粒子在基体PC中分散均匀,经硅烷偶联剂KH-550对SiO_2纳米粒子进行表面处理,分析了改性SiO_2纳米粒子对复合材料机械与加工性能的影响,并对复合材料进行了分析表征,探讨了无机刚性纳米粒子填充改性典型工程塑料PC的特点并探索其增强增韧的机理,研究了复合物的粘流变性能.结果表明,改性SiO_2纳米粒为球形,在PC基体中分散均匀,湿法改性制备的PC/SiO_2纳米粒子复合材料的力学拉伸性能和流变性能最好.
採用SiO_2納米粒子填充改性聚碳痠酯(PC),為使無機納米粒子在基體PC中分散均勻,經硅烷偶聯劑KH-550對SiO_2納米粒子進行錶麵處理,分析瞭改性SiO_2納米粒子對複閤材料機械與加工性能的影響,併對複閤材料進行瞭分析錶徵,探討瞭無機剛性納米粒子填充改性典型工程塑料PC的特點併探索其增彊增韌的機理,研究瞭複閤物的粘流變性能.結果錶明,改性SiO_2納米粒為毬形,在PC基體中分散均勻,濕法改性製備的PC/SiO_2納米粒子複閤材料的力學拉伸性能和流變性能最好.
채용SiO_2납미입자전충개성취탄산지(PC),위사무궤납미입자재기체PC중분산균균,경규완우련제KH-550대SiO_2납미입자진행표면처리,분석료개성SiO_2납미입자대복합재료궤계여가공성능적영향,병대복합재료진행료분석표정,탐토료무궤강성납미입자전충개성전형공정소료PC적특점병탐색기증강증인적궤리,연구료복합물적점류변성능.결과표명,개성SiO_2납미립위구형,재PC기체중분산균균,습법개성제비적PC/SiO_2납미입자복합재료적역학랍신성능화류변성능최호.
Modified SiO_2 nanoparticles were filled into polycarbonate (PC) by two different methods. In order to enable the inorganic nanoparticles dispersed evenly in the PC matrix, the silane coupling agent KH-550 was used to modify the surface of SiO_2 nanoparticles by wet treatment. The relationships between mechanical and processing properties of PC/SiO_2 composite and silica content were examined, and product performance characterized. The characteristics of rigid modified inorganic nanoparticles filled on a typical engineering plastic PC were also studied to explore the mechanism of its strength enhancement and the rheological properties of PC/SiO_2 composite. The results show that the modified SiO_2 spheres had uniform dispersion in PC matrix and PC/SiO_2 composite had good tensile strength and rheological effect.