中国化学工程学报(英文版)
中國化學工程學報(英文版)
중국화학공정학보(영문판)
CHINESE JOURNAL OF CHEMICAL ENGINEERING
2008年
2期
270-276
,共7页
童军茂%武占省%孙喜房%徐小琳%李春
童軍茂%武佔省%孫喜房%徐小琳%李春
동군무%무점성%손희방%서소림%리춘
acid-activated bentonite%pigment%model oil solution%adsorption kinetics
The textural properties of acid-activated bentonite (AAB), which were prepared using four different concentrations of sulfuric acid, were analyzed by adsorption-desorption isotherm of nitrogen using an automated specific surface area and porosity analyzer. The total pore volume, specific surface area and average pore diameter of these four kinds of AAB show a regular changing trend, increasing first and then decreasing, the optimum of which can be achieved at a sulfuric acid concentration of 25% (sample A25). The kinetic analysis of the adsorption ofβ-carotene and chlorophyll in model oil solutions, namely, xylene and edible oil solution, has been investigated by using AAB. Experimental results indicated that the adsorption data fit the pseudo-second-order model well. The whole adsorption process of the two pigments on AAB was divided basically into two parts: the initial adsorption of pigments was rapid in the first 10 min, followed by a slower adsorption process till equilibrium was attained at 60 min. In addition, the amount and rate of adsorption on A25 increase synchronously with the initial pigment concen-tration and temperature. The results showed that the adsorption kinetics behavior of AAB with respect to the pig- ments is not influence by the xylene and edible oil solution.