CAJ | 학술논문

为研究新型绝缘油天然酯与两种绝缘纸组成的酯-纸绝缘热老化特性,将天然酯-普通纸和天然酯-热稳定纸绝缘试品,在90℃、110℃和130℃下进行了399 d的热老化试验.结果表明:天然酯-纸绝缘中,相同老化条件下,热稳定纸聚合度和稳定聚合度都分别明显高于普通纸;通过热稳定纸中含有双氰胺的红外光谱分析,从官能团角度研究了热稳定纸抑制绝缘老化的两大机制.热稳定纸能吸附较多糠醛;对同一种酯-纸绝缘,糠醛仍可作为衡量变压器中酯-纸绝缘老化程度的参量;对不同绝缘纸的酯-纸绝缘,糠醛含量的差异不能表征它们之间绝缘纸老化程度的差异.研究了这两种不同酯-纸绝缘老化过程中,酯中微水含量变化规律的异同,从而建议使用天然酯的变压器,用热稳定纸作为与之匹配的固体绝缘材料,以利于酯在老化过程中保持较好绝缘性能.
위연구신형절연유천연지여량충절연지조성적지-지절연열노화특성,장천연지-보통지화천연지-열은정지절연시품,재90℃、110℃화130℃하진행료399 d적열노화시험.결과표명:천연지-지절연중,상동노화조건하,열은정지취합도화은정취합도도분별명현고우보통지;통과열은정지중함유쌍청알적홍외광보분석,종관능단각도연구료열은정지억제절연노화적량대궤제.열은정지능흡부교다강철;대동일충지-지절연,강철잉가작위형량변압기중지-지절연노화정도적삼량;대불동절연지적지-지절연,강철함량적차이불능표정타문지간절연지노화정도적차이.연구료저량충불동지-지절연노화과정중,지중미수함량변화규률적이동,종이건의사용천연지적변압기,용열은정지작위여지필배적고체절연재료,이리우지재노화과정중보지교호절연성능.
In order to compare the properties of natural ester impregnated Kraft paper and thermally upgraded paper, sealed aging vessels containing copper, insulation paper (Kraft paper and thermally upgraded paper), and natural ester were aged at 90℃, 110℃, and 130℃ 399 days. The results show that both degree of polymerization(DP) and leveling-off degree of polymerization (LODP) for thermally upgraded paper were higher than the ones of Kraft paper at the same aging condition. The infrared spectrum evidence was given that there was dicyandiamide in thermally upgraded paper, and the aging resistance mechanisms of thermally upgraded paper were analyzed. Furfural can be absorbed by thermally upgraded paper and can be used to monitor the aging condition of a certain natural ester impregnated paper insulation. However, furfural can not be used to compare the aging condition of different types of paper immersed in natural ester. The different disciplinarians of the water content in natural ester were analyzed and the suggestion is given that the thermally upgraded paper are more suitable for natural ester impregnated paper insulation.