新型炭材料
新型炭材料
신형탄재료
NEW CARBON MATERIALS
2011年
3期
171-179
,共9页
符若文%李争晖%梁业如%李峰%徐飞%吴丁财
符若文%李爭暉%樑業如%李峰%徐飛%吳丁財
부약문%리쟁휘%량업여%리봉%서비%오정재
层次孔炭材料%合成方法%储能
層次孔炭材料%閤成方法%儲能
층차공탄재료%합성방법%저능
Hierarchical porous carbons%Preparation methods%Energy storage
层次孔炭材料呈合理的微孔-中孔/大孔结构及孔径分布,具有高的电化学活性表面、极短的扩散距离和较高的传质速率,在用作储能器件电极材料时,表现出优异的功率特性.通过综述近来年层次孔炭材料的设计制备及其在储能领域的应用进展,重点介绍了本课题组自2008年以来的研究成果,进而展望了层次孔炭材料的发展方向.指出:层次孔炭材料主要通过模板法或模板-活化联合法制备.这两种方法可以实现炭材料纳米结构的精确调控.最近,开发出来的更简易的免模板法展现出较好的应用前景.
層次孔炭材料呈閤理的微孔-中孔/大孔結構及孔徑分佈,具有高的電化學活性錶麵、極短的擴散距離和較高的傳質速率,在用作儲能器件電極材料時,錶現齣優異的功率特性.通過綜述近來年層次孔炭材料的設計製備及其在儲能領域的應用進展,重點介紹瞭本課題組自2008年以來的研究成果,進而展望瞭層次孔炭材料的髮展方嚮.指齣:層次孔炭材料主要通過模闆法或模闆-活化聯閤法製備.這兩種方法可以實現炭材料納米結構的精確調控.最近,開髮齣來的更簡易的免模闆法展現齣較好的應用前景.
층차공탄재료정합리적미공-중공/대공결구급공경분포,구유고적전화학활성표면、겁단적확산거리화교고적전질속솔,재용작저능기건전겁재료시,표현출우이적공솔특성.통과종술근래년층차공탄재료적설계제비급기재저능영역적응용진전,중점개소료본과제조자2008년이래적연구성과,진이전망료층차공탄재료적발전방향.지출:층차공탄재료주요통과모판법혹모판-활화연합법제비.저량충방법가이실현탄재료납미결구적정학조공.최근,개발출래적경간역적면모판법전현출교호적응용전경.
Hierarchical porous carbons (HPCs) possess a multimodal pore size distribution of micro-, meso-, and/or macropores, and thus show high electrochemically accessible surface area, short diffusion distance, and high mass transfer rate when used as electrode materials in energy storage devices. Because of this, HPCs show excellent rate capabilities and have attracted considerable attention in recent years. Normally, HPCs are prepared by templating methods or combined templating/activation methods, in which carbons are inverse replicas of the template and the pore structure parameters of HPCs can be easily tuned. Recently, simpler template-free methods have been developed and show a promising future. In this review, we describe the recent advances in design, preparation, and electrochemical performance of HPCs, with particular attention to the main achievements using HPCs developed in our groups since 2008. Finally we give a brief outlook.