稀有金属
稀有金屬
희유금속
CHINESE JOURNAL OF RARE METALS
2010年
1期
48-52
,共5页
胡忠武%李中奎%殷涛%郭林江%张清%郑剑平
鬍忠武%李中奎%慇濤%郭林江%張清%鄭劍平
호충무%리중규%은도%곽림강%장청%정검평
Mo-Nb合金单晶%固溶强化%高温强度%高温稳态蠕变速率
Mo-Nb閤金單晶%固溶彊化%高溫彊度%高溫穩態蠕變速率
Mo-Nb합금단정%고용강화%고온강도%고온은태연변속솔
Mo-Nb alloy single crystal%solid-solution strengthening%high temperature strength%high temperature creep rate
研究了晶向为<111>Mo-Nb合金单晶的高温力学性能.实验结果表明,随着少量溶质原子Nb的加入,Mo-Nb合金单晶的高温强度获得了明显的提高.在1873 K和Nb含量在0~6%范围内时(文中合金元素Nb含量均为质量百分比,下同),Nb含量每增大1%,材料的高温屈服强度就增加约16~25 MPa,当Nb含量在0~3%范围内时,随着Nb含量的增加,塑性急剧下降,而在3%~6%范围内时其下降幅度趋于平缓;同时,随着Nb浓度的增大,更多的Nb溶质原子增大了原子间扩散阻力,使材料高温稳态蠕变率减小,大大提高了材料的高温抗蠕变性能;在1773 K/10 MPa时Mo-Nb合金单晶的稳态蠕变率较纯Mo单晶的降低了3~4个数量级,分析认为其蠕变机制为扩散蠕变.
研究瞭晶嚮為<111>Mo-Nb閤金單晶的高溫力學性能.實驗結果錶明,隨著少量溶質原子Nb的加入,Mo-Nb閤金單晶的高溫彊度穫得瞭明顯的提高.在1873 K和Nb含量在0~6%範圍內時(文中閤金元素Nb含量均為質量百分比,下同),Nb含量每增大1%,材料的高溫屈服彊度就增加約16~25 MPa,噹Nb含量在0~3%範圍內時,隨著Nb含量的增加,塑性急劇下降,而在3%~6%範圍內時其下降幅度趨于平緩;同時,隨著Nb濃度的增大,更多的Nb溶質原子增大瞭原子間擴散阻力,使材料高溫穩態蠕變率減小,大大提高瞭材料的高溫抗蠕變性能;在1773 K/10 MPa時Mo-Nb閤金單晶的穩態蠕變率較純Mo單晶的降低瞭3~4箇數量級,分析認為其蠕變機製為擴散蠕變.
연구료정향위<111>Mo-Nb합금단정적고온역학성능.실험결과표명,수착소량용질원자Nb적가입,Mo-Nb합금단정적고온강도획득료명현적제고.재1873 K화Nb함량재0~6%범위내시(문중합금원소Nb함량균위질량백분비,하동),Nb함량매증대1%,재료적고온굴복강도취증가약16~25 MPa,당Nb함량재0~3%범위내시,수착Nb함량적증가,소성급극하강,이재3%~6%범위내시기하강폭도추우평완;동시,수착Nb농도적증대,경다적Nb용질원자증대료원자간확산조력,사재료고온은태연변솔감소,대대제고료재료적고온항연변성능;재1773 K/10 MPa시Mo-Nb합금단정적은태연변솔교순Mo단정적강저료3~4개수량급,분석인위기연변궤제위확산연변.
The high temperature mechanical properties of Mo-Nb alloy single crystals with<111>orientation were studied.The experimental results showed that significant increase in high temperature mechanical properties could be achieved with small amount addition of substitutional alloying element Nb.The yield strength at 1873 K increased approximately 16~25 MPa with Nb increasing 1%in the range of 0~6%Nb.The elongation of materials drastically decreased from 0 to 3%.but it appreciably reduced when the concentration of Nb was in the range of 3%~6%.On the other hand.the steady state creep rates significantly decreased with addition of niobium due to the augment of the force to retard directional diffusion among atoms.The steady state creep rate of Mo-Nb alloy single crystal was three to four orders of magnitude lower than that of purity Mo single crystal at 1773 K/10 MPa.Its creep mechanism of Mo-Nballoy single crystals was a diffusion creep.