CAJ | 학술논문

以丙烯酰胺(AM)、甲基丙烯酰氧乙基三甲基氯化铵(DMC)、二甲基二烯丙基氯化铵(DMDAAC)为单体原料,采用水溶液聚合技术制备了粉末型阳离子三元聚合物P(AM/DMC/DMDAAC).采用红外光谱、核磁共振和热重分析对所制备阳离子聚合物进行了结构和组成表征,并利用电导率仪和布氏黏度计对其溶解性及其溶液黏度进行了测定.结果表明:合成的产物为P(AM/DMC/DMDAAC),具有良好的热稳定性和溶解性.三元聚合物的表观黏度随着聚合物质量浓度的增加先减小后增加,随剪切速率的增加而下降.在不同的外加盐溶液里,三元聚合物溶液表现出明显的反聚电解质行为.
이병희선알(AM)、갑기병희선양을기삼갑기록화안(DMC)、이갑기이희병기록화안(DMDAAC)위단체원료,채용수용액취합기술제비료분말형양리자삼원취합물P(AM/DMC/DMDAAC).채용홍외광보、핵자공진화열중분석대소제비양리자취합물진행료결구화조성표정,병이용전도솔의화포씨점도계대기용해성급기용액점도진행료측정.결과표명:합성적산물위P(AM/DMC/DMDAAC),구유량호적열은정성화용해성.삼원취합물적표관점도수착취합물질량농도적증가선감소후증가,수전절속솔적증가이하강.재불동적외가염용액리,삼원취합물용액표현출명현적반취전해질행위.
The pulverous cationic terpolymers P (AM/DMC/DMDAAC) were prepared by aqueous solution copolymerization with acrylamide (AM) , (2-methacryloyloxyethyl) trimethylammonium chloride (DMC) and dimethyldiallylammonium chloride (DMDAAC) as the raw materials. The cationic copolymers were characterized by means of Fourier Transform Infra-Red,~1H-NMR and Thermogravimetry. The solubility and viscosity of terpolymer were measured by means of Conductivity Meter and Brookfield Programmable DV- II + Viscometer, respectively. The results indicate that the product is the terpolymer of AM, DMC and DMDAAC, which has better thermal stability and solubility. With increasing the terpolymer mass concentration, the apparent viscosities of terpolymer solution first decrease and then increase, however, the apparent viscosities decrease with increasing shear rate. In the different salts solutions, the terpolymer solution exhibits obvious antipolyelectrolyte characteristics.