CAJ | 학술논문

综述了近年来聚烯烃嵌段共聚物多种合成方法,包括:活性聚合方法(阴离子、阳离子活性聚合,基团转移聚合,自由基活性聚合,配位活性聚合)、正离子聚合转化法、力化学方法、缩聚法和特殊引发剂法等.同时讨论了各种合成方法的优点及局限性,探讨了其在工业应用上的重要意义.
종술료근년래취희경감단공취물다충합성방법,포괄:활성취합방법(음리자、양리자활성취합,기단전이취합,자유기활성취합,배위활성취합)、정리자취합전화법、력화학방법、축취법화특수인발제법등.동시토론료각충합성방법적우점급국한성,탐토료기재공업응용상적중요의의.
The efficient synthesis of well-defined block copolymers was very important both for research and industry.This article summarized the methods for the preparation of block copolymers.Examples include anionic,cationic,flee-radical polymerizations,coordination polymerization and other methods that were useful for the preparation of these hybrid materials.In addition,the advantage and disadvantage of each method,and its potential application in industry was described.