无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2008年
6期
843-847
,共5页
碳硼烷%硫%半夹心铑配合物
碳硼烷%硫%半夾心銠配閤物
탄붕완%류%반협심로배합물
carborane%sulfur%half-sandwich rhodium
室温下,18-电子体系的半夹心铑配合物Cp*Rh(L)S2C2(B10H10) (L=4-ClCH2-C6H4N(2a),4-CH3SCH2-C6H4N(2b))可以通过16-电子体系的半夹心铑配合物[Cp2Rh[S2C2(B10H10)]与吡啶衍生物合成.化合物通过IR、1H NMR和元素分析进行了表征,并用X-射线单晶衍射测定了配合物2a和2b的单晶结构.
室溫下,18-電子體繫的半夾心銠配閤物Cp*Rh(L)S2C2(B10H10) (L=4-ClCH2-C6H4N(2a),4-CH3SCH2-C6H4N(2b))可以通過16-電子體繫的半夾心銠配閤物[Cp2Rh[S2C2(B10H10)]與吡啶衍生物閤成.化閤物通過IR、1H NMR和元素分析進行瞭錶徵,併用X-射線單晶衍射測定瞭配閤物2a和2b的單晶結構.
실온하,18-전자체계적반협심로배합물Cp*Rh(L)S2C2(B10H10) (L=4-ClCH2-C6H4N(2a),4-CH3SCH2-C6H4N(2b))가이통과16-전자체계적반협심로배합물[Cp2Rh[S2C2(B10H10)]여필정연생물합성.화합물통과IR、1H NMR화원소분석진행료표정,병용X-사선단정연사측정료배합물2a화2b적단정결구.
The 18-electron dithiolato carborane complexes Cp*Rh(L)S2C2(B10H10) (L=4-(chloromethyl) pyridine (2a),4-(methylthiomethyl) pyridine (2b)) were synthesized from the 16e half-sandwich rhodium complexe [Cp*Rh(L)S2C2(B10H10)] and pyridine derivatives (L) at room temperature. The complexes have been fully characterized by their IR and 1H NMR spectroscopy,as well as elemental analysis. The molecular structures of 2a and 2b were established through X-ray crystal structure analysis. CCDC;679789,2a; 679790,2b.
