CAJ | 학술논문

咔咯(Corrole)是由4个吡咯共轭相连而形成的新型卟啉类大环配合物,它们能稳定结合具有较高氧化态的金属离子,所形成的金属配合物具有比较独特的光化学、电化学、光物理和光生物性质.研究表明,咔咯是一类非常重要的多功能配合物,它们在精细化学品领域具有广阔的应用前景.对咔咯配合物的主要合成方法、配合物用作精细化工催化剂、燃料电池电极催化材料、抗肿瘤光敏剂、电化学传感器和非线性光学材料等方面的研究和应用作了综述.
잡각(Corrole)시유4개필각공액상련이형성적신형계람류대배배합물,타문능은정결합구유교고양화태적금속리자,소형성적금속배합물구유비교독특적광화학、전화학、광물리화광생물성질.연구표명,잡각시일류비상중요적다공능배합물,타문재정세화학품영역구유엄활적응용전경.대잡각배합물적주요합성방법、배합물용작정세화공최화제、연료전지전겁최화재료、항종류광민제、전화학전감기화비선성광학재료등방면적연구화응용작료종술.
Corroles are novel porphyrin-like macrocyclic complexes with four connected pyrroles in the molecule.Corroles can stabilize metal ions with higher oxidation states,leading to the formation of metallocorroles which have unique photochemical,electrochemical,photophysical and photobiological properties.The research results indicate that corroles are very important multifunctional complexes with wide applications in the area of fine chemicals.The main methods for synthesis of corroles,and the recent progress in research and application of the complexes as catalysts in fine chemical industry,electrode catalytic materials in fuel cell,anti-tumor photosensitizer,electrochemical sensors and non-linear materials were reviewed.