华南理工大学学报(自然科学版)
華南理工大學學報(自然科學版)
화남리공대학학보(자연과학판)
JOURNAL OF SOUTH CHINA UNIVERSITY OF TECHNOLOGY(NATURAL SCIENCE EDITION)
2009年
12期
28-31,36
,共5页
任碧野%施璐%程志毓%单化众%李崇清%童真
任碧野%施璐%程誌毓%單化衆%李崇清%童真
임벽야%시로%정지육%단화음%리숭청%동진
二茂铁%树形两亲分子%电化学行为
二茂鐵%樹形兩親分子%電化學行為
이무철%수형량친분자%전화학행위
ferrocene%dendritic amphiphilic molecule%electrochemical behavior
以3,4,5-三羟基苯甲酸甲酯为母体,经与11-二茂铁基溴代十一烷进行亲核取代反应合成了3,4,5-三-(11-二茂铁基)十一烷氧基苯甲酸.通过元素分析、核磁共振、傅里叶变换红外及紫外-可见光谱等对产物进行了表征,并利用循环伏安法、线性扫描伏安法、常规脉冲伏安法、计时电流法和计时电量法研究了产物的电化学行为, 测定了其电化学参数. 结果表明,该二茂铁基两亲分子在DMF溶液中具有良好的氧化还原可逆性, 是由扩散控制的可逆过程, 且3个二茂铁基团之间没有强相互作用而显示等同的氧化还原活性.
以3,4,5-三羥基苯甲痠甲酯為母體,經與11-二茂鐵基溴代十一烷進行親覈取代反應閤成瞭3,4,5-三-(11-二茂鐵基)十一烷氧基苯甲痠.通過元素分析、覈磁共振、傅裏葉變換紅外及紫外-可見光譜等對產物進行瞭錶徵,併利用循環伏安法、線性掃描伏安法、常規脈遲伏安法、計時電流法和計時電量法研究瞭產物的電化學行為, 測定瞭其電化學參數. 結果錶明,該二茂鐵基兩親分子在DMF溶液中具有良好的氧化還原可逆性, 是由擴散控製的可逆過程, 且3箇二茂鐵基糰之間沒有彊相互作用而顯示等同的氧化還原活性.
이3,4,5-삼간기분갑산갑지위모체,경여11-이무철기추대십일완진행친핵취대반응합성료3,4,5-삼-(11-이무철기)십일완양기분갑산.통과원소분석、핵자공진、부리협변환홍외급자외-가견광보등대산물진행료표정,병이용순배복안법、선성소묘복안법、상규맥충복안법、계시전류법화계시전량법연구료산물적전화학행위, 측정료기전화학삼수. 결과표명,해이무철기량친분자재DMF용액중구유량호적양화환원가역성, 시유확산공제적가역과정, 차3개이무철기단지간몰유강상호작용이현시등동적양화환원활성.
2,3,4-tri-(11-ferroncenyl)decyl-1-yloxy benzoic acid was synthesized via the nucleophilic displacement reaction of methyl 3,4,5-trihydroxybenzoate and 11-ferroncenyl-1-bromoundecane. The compound was then characterized by means of elemental analysis, NMR, FT-IR and UV-Vis, etc. Moreover, the electrochemical behaviour of the compound was investigated using the cyclic voltammetry, the linear sweep voltammetry, the normal pulse voltammetry, the chronoampermetry and the chronocoulometry, and the electrochemical parameters of the compound were finally determined. The results indicate that the dendritic amphiphilic molecules in DMF solution exhibit good diffusion-controlled redox reversibility, and that the three ferroncenyl substituents of the compound do not interact strongly with one another but they exhibit similar redox activity.