三峡环境与生态
三峽環境與生態
삼협배경여생태
CHONGQING ENVIRONMENTAL SCIENCE
2012年
1期
31-36
,共6页
李在钟%孙群%朱虹%刘子岩
李在鐘%孫群%硃虹%劉子巖
리재종%손군%주홍%류자암
荧蒽%吸附模型%pH值%离子强度%腐殖酸
熒蒽%吸附模型%pH值%離子彊度%腐殖痠
형은%흡부모형%pH치%리자강도%부식산
fluoranthene%sorption model%pH ionic strength%humic acid
以多环芳烃荧蒽为研究对象,通过模拟吸附实验,研究了嘉陵江重庆段底泥对荧葸的吸附特性及其机理,进一步探讨了离子强度、pH值及腐殖酸(HA)对吸附性能的影响。结果表明:嘉陵江底泥对水体中荧葸的吸附曲线较好地符合传统的线性分配模型和Freundlich等温吸附模型。随着pH值增加,荧蒽在底泥上的吸附容量减小;离子强度的增大有利于荧蒽在底泥上的吸附;腐殖酸的加入显著增强了荧葸在底泥上的吸附能力,其吸附系数与腐殖酸含量呈线性正相关。
以多環芳烴熒蒽為研究對象,通過模擬吸附實驗,研究瞭嘉陵江重慶段底泥對熒葸的吸附特性及其機理,進一步探討瞭離子彊度、pH值及腐殖痠(HA)對吸附性能的影響。結果錶明:嘉陵江底泥對水體中熒葸的吸附麯線較好地符閤傳統的線性分配模型和Freundlich等溫吸附模型。隨著pH值增加,熒蒽在底泥上的吸附容量減小;離子彊度的增大有利于熒蒽在底泥上的吸附;腐殖痠的加入顯著增彊瞭熒葸在底泥上的吸附能力,其吸附繫數與腐殖痠含量呈線性正相關。
이다배방경형은위연구대상,통과모의흡부실험,연구료가릉강중경단저니대형사적흡부특성급기궤리,진일보탐토료리자강도、pH치급부식산(HA)대흡부성능적영향。결과표명:가릉강저니대수체중형사적흡부곡선교호지부합전통적선성분배모형화Freundlich등온흡부모형。수착pH치증가,형은재저니상적흡부용량감소;리자강도적증대유리우형은재저니상적흡부;부식산적가입현저증강료형사재저니상적흡부능력,기흡부계수여부식산함량정선성정상관。
Experiments were carried out to investigate characteristics and mechanism of sorption of fluoranthene on surface sediment in the Jialing River. Moreover, impacts from pH value, ionic strength and Humic acid(HA)on the sorption experiments were assessed as well. Results suggest that the sorption curve of fluoranthene on surface sedi- ment was in line with the traditional linear partition model and Freundlich sorption model. The adsorption capacity of surface sediment to fluoranthene was declined along with increase in pH value, while increase in ionic strength ap- pear to facilitate sorption of fluoranthene on surface sediment;similarly, growing HA level significantly increased adsorption capacity. The association between partition coefficient and HA prove to be positively linear correlated.